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Description
  • We introduce a mathematical model of one electron transfer (metal A/cation A+ and ferrocyanide/ferricyanide) in a microfluidic electrochemical cell. This cell is characterized by the absence of well stirred bulk and an undefined reference value of electric potential. First, we will introduce mathematical description of reaction-transport processes in this cell with the use of an alternative kinetic scheme. The scheme allows for the simulation of electrochemical reactions far from the thermodynamic equilibrium. Obtained current-voltage characteristics will be discussed. Further, we show the abilities of our model to simulate cyclic voltammetry measurement.
  • We introduce a mathematical model of one electron transfer (metal A/cation A+ and ferrocyanide/ferricyanide) in a microfluidic electrochemical cell. This cell is characterized by the absence of well stirred bulk and an undefined reference value of electric potential. First, we will introduce mathematical description of reaction-transport processes in this cell with the use of an alternative kinetic scheme. The scheme allows for the simulation of electrochemical reactions far from the thermodynamic equilibrium. Obtained current-voltage characteristics will be discussed. Further, we show the abilities of our model to simulate cyclic voltammetry measurement. (en)
Title
  • Mathematical modeling of electrochemical cell in microfluidic chips
  • Mathematical modeling of electrochemical cell in microfluidic chips (en)
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  • Mathematical modeling of electrochemical cell in microfluidic chips
  • Mathematical modeling of electrochemical cell in microfluidic chips (en)
skos:notation
  • RIV/60461373:22340/13:43895449!RIV14-MSM-22340___
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  • P(IAA401280904), S
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  • 86589
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  • RIV/60461373:22340/13:43895449
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  • microfluidics, nanofluidics; microchip; electron mediators; non-equilibrium model; mathematical modeling; Faradaic reactions (en)
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  • [16E3B245E41A]
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  • Tatranské Matliare
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  • Bratislava
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  • Proceedings of the 40th International Conference of Slovak Society of Chemical Engineering
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  • Fišer, Jan
  • Šnita, Dalimil
  • Přibyl, Michal
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number of pages
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  • Slovak Society of Chemical Engineering
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  • 978-80-89475-09-4
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  • 22340
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