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  • In the high-impact polystyrene (HIPS) production it is desirable that a two-level (the so-called salami) morphology develops: (i) irregular sub-micron polystyrene (PS) domains are dispersed in micron-sized polybutadiene (PB) particles, and (ii) oval PB particles of the size of several microns are dispersed in the continuum PS phase. We have used advanced tools of mathematical modeling as well as experimental methods to approach problems related to HIPS: (i) prediction of morphology-dependent impact resistance, (ii) characterization of HIPS morphology and thermodynamics of its components, and (iii) evolution of HIPS morphology. The morphology strongly affects the impact resistance and the gloss of the material. Mathematical model is centered about mass balances of species in the polymer/polymer/monomer system. The generalized gradient of chemical potential is considered as the driving force of diffusion transport instead of the usual concentration gradient employed in the simple Fick?s law. The general
  • In the high-impact polystyrene (HIPS) production it is desirable that a two-level (the so-called salami) morphology develops: (i) irregular sub-micron polystyrene (PS) domains are dispersed in micron-sized polybutadiene (PB) particles, and (ii) oval PB particles of the size of several microns are dispersed in the continuum PS phase. We have used advanced tools of mathematical modeling as well as experimental methods to approach problems related to HIPS: (i) prediction of morphology-dependent impact resistance, (ii) characterization of HIPS morphology and thermodynamics of its components, and (iii) evolution of HIPS morphology. The morphology strongly affects the impact resistance and the gloss of the material. Mathematical model is centered about mass balances of species in the polymer/polymer/monomer system. The generalized gradient of chemical potential is considered as the driving force of diffusion transport instead of the usual concentration gradient employed in the simple Fick?s law. The general (en)
Title
  • Modeling of morphology evolution of high-impact polystyrene
  • Modeling of morphology evolution of high-impact polystyrene (en)
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  • Modeling of morphology evolution of high-impact polystyrene
  • Modeling of morphology evolution of high-impact polystyrene (en)
skos:notation
  • RIV/60461373:22340/10:00023432!RIV11-MPO-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(FT-TA3/110), P(KAN208240651), S, Z(MSM6046137306)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 271878
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/10:00023432
http://linked.open...riv/jazykVysledku
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  • High-impact polystyrene; spinodal decomposition; nucleation; modeling (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [77727070A0EA]
http://linked.open...v/mistoKonaniAkce
  • Praha
http://linked.open...i/riv/mistoVydani
  • Praha
http://linked.open...i/riv/nazevZdroje
  • CHISA 2010
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Kosek, Juraj
  • Zubov, Alexandr
  • Vonka, Michal
  • Šeda, Libor
  • Bobák, Marek
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Process Engineering Publisher, Novosad, J.
https://schema.org/isbn
  • 978-80-02-02210-7
http://localhost/t...ganizacniJednotka
  • 22340
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