About: Extraction of europium and cerium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 600     Goto   Sponge   NotDistinct   Permalink

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  • Solvent extraction of microamounts of europium and cerium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of polyethylene glycol PEG 600 (L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+, H2L2+ and ML3+ (M3+ = Eu3+, Ce3+; L = PEG 600) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It was found that the stability constants of the EuL3+ and CeL3+ cationic complex species (L = PEG 600) in water-saturated nitrobenzene are the same.
  • Solvent extraction of microamounts of europium and cerium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of polyethylene glycol PEG 600 (L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+, H2L2+ and ML3+ (M3+ = Eu3+, Ce3+; L = PEG 600) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It was found that the stability constants of the EuL3+ and CeL3+ cationic complex species (L = PEG 600) in water-saturated nitrobenzene are the same. (en)
Title
  • Extraction of europium and cerium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 600
  • Extraction of europium and cerium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 600 (en)
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  • Extraction of europium and cerium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 600
  • Extraction of europium and cerium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and polyethylene glycol PEG 600 (en)
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  • RIV/60461373:22340/10:00023363!RIV11-MSM-22340___
http://linked.open...avai/riv/aktivita
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  • S, Z(AV0Z40500505), Z(MSM4977751303)
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  • 1
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  • 258598
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  • RIV/60461373:22340/10:00023363
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  • Extraction; Europium; Cerium; Nitrobenzene; Dicarbollylcobaltate; Polyethylene glycol PEG 600; Complexes (en)
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  • DE - Spolková republika Německo
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  • [7B2DC85472F9]
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  • Journal of Radioanalytical and Nuclear Chemistry
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  • 283
http://linked.open...iv/tvurceVysledku
  • Makrlík, E.
  • Vaňura, Petr
  • Sedláková, Z.
http://linked.open...ain/vavai/riv/wos
  • 000274333000021
http://linked.open...n/vavai/riv/zamer
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  • 0236-5731
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  • 22340
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