About: Temperature dependences of limiting activity coefficients and Henry`s law constants for N-methylpyrrolidone, pyridine, and piperidine in water

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Limiting activity coefficients of N-methylpyrrolidone (NMP), pyridine, and piperidine in water were measured at several temperatures in the range from 333 K to 373 K. Three experimental techniques, namely Rayleigh distillation, differential distillation, and the method of circulation still, were employed for the purpose. A comprehensive review is further presented of experimental data on the limiting activity coefficients, infinite dilution partial molar excess enthalpies, and heat capacities of these aqueous solutes. Additionally, to verify fragmentary literature information, solution heat capacity for NMP was also determined in this work using Picker flow microcalorimeter. For each solute, the compiled data were critically evaluated and together with the data measured in this work correlated with a suitable model equation providing adequate simultaneous description of the equilibrium measurements and the calorimetric information. As a result, a recommended thermodynamically consistent temperature de Limiting activity coefficients of N-methylpyrrolidone (NMP), pyridine, and piperidine in water were measured at several temperatures in the range from 333 K to 373 K. Three experimental techniques, namely Rayleigh distillation, differential distillation, and the method of circulation still, were employed for the purpose. A comprehensive review is further presented of experimental data on the limiting activity coefficients, infinite dilution partial molar excess enthalpies, and heat capacities of these aqueous solutes. Additionally, to verify fragmentary literature information, solution heat capacity for NMP was also determined in this work using Picker flow microcalorimeter. For each solute, the compiled data were critically evaluated and together with the data measured in this work correlated with a suitable model equation providing adequate simultaneous description of the equilibrium measurements and the calorimetric information. As a result, a recommended thermodynamically consistent temperature de (en)
Title	Temperature dependences of limiting activity coefficients and Henry`s law constants for N-methylpyrrolidone, pyridine, and piperidine in water Temperature dependences of limiting activity coefficients and Henry`s law constants for N-methylpyrrolidone, pyridine, and piperidine in water (en)
skos:prefLabel	Temperature dependences of limiting activity coefficients and Henry`s law constants for N-methylpyrrolidone, pyridine, and piperidine in water Temperature dependences of limiting activity coefficients and Henry`s law constants for N-methylpyrrolidone, pyridine, and piperidine in water (en)
skos:notation	RIV/60461373:22340/09:00021855!RIV10-MSM-22340___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika	282
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Dohnal, Vladimír Bernauer, Milan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	345716
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/09:00021855
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Limiting activity coefficient; Henry`s law constant; Temperature dependence; N-methylpyrrolidone; pyridine; piperidine (en)
http://linked.open.../riv/klicoveSlovo	N-methylpyrrolidone Limiting activity coefficient Temperature dependence pyridine Henry`s law constant piperidine
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[0C224BA480BE]
http://linked.open...i/riv/nazevZdroje	Fluid Phase Equilibria
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	2009
http://linked.open...iv/tvurceVysledku	Dohnal, Vladimír Bernauer, Milan
http://linked.open...ain/vavai/riv/wos	000268120200005
http://linked.open...n/vavai/riv/zamer	Physico-chemical methods of analysis and characterization of chemical systems and biosystems
issn	0378-3812
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	22340

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