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Description
  • Z extrakčních dat v systému vodný roztok sole kationtu - nitrobenzen ? strontnatá sůl dikarbollylkobaltitanu byla spočtena rovnovážná extrakční konstanta reakce M2+ (aq) + 1.Sr2+ (nb) 1.M2+ (nb) + Sr2+ (aq) (M2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Fe2+, Co2+, a Ni2+; 1 = valinomycin; aq =vodná fáze, nb = nitrobenzenová fáze). Konstanta stability komplexu 1.M2+ v nitrobenzenu, nasyceném vodou roste v pořadí Fe2+ < Cd2+, Co2+ < Ni2+ < UO22+, Zn2+ < Cu2+ < Pb2+. (cs)
  • From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+ (aq) + 1.Sr2+ (nb) 1.M2+ (nb) + Sr2+ (aq) taking place in the two-phase water-nitrobenzene system (M2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Fe2+, Co2+, and Ni2+; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the 1.M2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the order Fe2+ < Cd2+, Co2+ < Ni2+ < UO22+, Zn2+ < Cu2+ < Pb2+.
  • From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+ (aq) + 1.Sr2+ (nb) 1.M2+ (nb) + Sr2+ (aq) taking place in the two-phase water-nitrobenzene system (M2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Fe2+, Co2+, and Ni2+; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the 1.M2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the order Fe2+ < Cd2+, Co2+ < Ni2+ < UO22+, Zn2+ < Cu2+ < Pb2+. (en)
Title
  • Experimental evidences for some unusual divalent cation complexes of valinomycin
  • Experimental evidences for some unusual divalent cation complexes of valinomycin (en)
  • Experimentální důkaz tvorby komplexů některých dvojmocných kationtů s valinomycinem (cs)
skos:prefLabel
  • Experimental evidences for some unusual divalent cation complexes of valinomycin
  • Experimental evidences for some unusual divalent cation complexes of valinomycin (en)
  • Experimentální důkaz tvorby komplexů některých dvojmocných kationtů s valinomycinem (cs)
skos:notation
  • RIV/60461373:22340/08:00020705!RIV09-MSM-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/05/2667), Z(MSM4977751303), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 367189
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/08:00020705
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • antibiotics; macrocycles; complexation; stability constants; valinomycin (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [5F0B927D49F2]
http://linked.open...i/riv/nazevZdroje
  • Monatshefte für Chemie
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 139
http://linked.open...iv/tvurceVysledku
  • Makrlík, E.
  • Vaňura, Petr
  • Selucký, P.
http://linked.open...ain/vavai/riv/wos
  • 000256324700003
http://linked.open...n/vavai/riv/zamer
issn
  • 0026-9247
number of pages
http://localhost/t...ganizacniJednotka
  • 22340
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