About: Stability constants of complexes of Li+, H3O+, NH4+ and Ag+ with hexaethyl calix[6]arene hexaacetate in nitrobenzene saturated with water

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About: Stability constants of complexes of Li+, H3O+, NH4+ and Ag+ with hexaethyl calix[6]arene hexaacetate in nitrobenzene saturated with water Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Z extrakčních dat byla stanovena rovnovážná extrakční konstanta reakce M+(aq)+NaL+( nb) ML+( nb)+ Na+(aq) (M+ = Li+, H3O+, NH4+, Ag+; L = hexaethyl kalix[ 6] aren hexaacetát; aq =vodná fáze, nb = nitrobenzenová fáze) a konstanty stability komplexu ML2+ v nitrobenzenu, nasyceném vodou. Hodnoty konstant stability rostou v řadě H3O+<NH4+<Li+ <Ag+. (cs) From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq)+NaL+( nb) ML+( nb)+ Na+(aq) taking place in the two-phase water - nitrobenzene system (M+ = Li+, H3O+, NH4+, Ag+; L = hexaethyl calix[ 6] arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the ML+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the cation order H3O+<NH4+<Li+ <Ag+. From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq)+NaL+( nb) ML+( nb)+ Na+(aq) taking place in the two-phase water - nitrobenzene system (M+ = Li+, H3O+, NH4+, Ag+; L = hexaethyl calix[ 6] arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the ML+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the cation order H3O+<NH4+<Li+ <Ag+. (en)
Title	Stability constants of complexes of Li+, H3O+, NH4+ and Ag+ with hexaethyl calix[6]arene hexaacetate in nitrobenzene saturated with water Konstanty stability komplexů Li+, H3O+, NH4+ a Ag+ s hexaethyl kalix[6]aren hexaacetátem v nitrobenzenu, nasyceném vodou (cs) Stability constants of complexes of Li+, H3O+, NH4+ and Ag+ with hexaethyl calix[6]arene hexaacetate in nitrobenzene saturated with water (en)
skos:prefLabel	Stability constants of complexes of Li+, H3O+, NH4+ and Ag+ with hexaethyl calix[6]arene hexaacetate in nitrobenzene saturated with water Konstanty stability komplexů Li+, H3O+, NH4+ a Ag+ s hexaethyl kalix[6]aren hexaacetátem v nitrobenzenu, nasyceném vodou (cs) Stability constants of complexes of Li+, H3O+, NH4+ and Ag+ with hexaethyl calix[6]arene hexaacetate in nitrobenzene saturated with water (en)
skos:notation	RIV/60461373:22340/08:00020703!RIV09-MSM-22340___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM4977751303), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Vaňura, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	396859
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/08:00020703
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	individual extraction constants; univalent cations; metals; extraction (en)
http://linked.open.../riv/klicoveSlovo	metals univalent cations extraction individual extraction constants
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[01034CFA14E6]
http://linked.open...i/riv/nazevZdroje	Journal of Radioanalytical and Nuclear Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	277
http://linked.open...iv/tvurceVysledku	Makrlík, E. Vaňura, Petr
http://linked.open...ain/vavai/riv/wos	000257464000029
http://linked.open...n/vavai/riv/zamer	Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů. Physico-chemical methods of analysis and characterization of chemical systems and biosystems
issn	0236-5731
number of pages	3 (xsd:int)
http://localhost/t...ganizacniJednotka	22340

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