About: Simultaneous correlation of VLE and LLE experimental data for system with upper critical solubility temperature (tetraglyme ? decane)

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About: Simultaneous correlation of VLE and LLE experimental data for system with upper critical solubility temperature (tetraglyme ? decane) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Properties related to vapor-liquid and liquid-liquid equilibria have been measured, collected from literature and subsequently simultaneously correlated using Redlich-Kister equation for the binary system Tetraglyme + Decane. IGS method was used for measurement of limiting activity coefficients of alkanes (C5-C8) in Tetraglyme in temperature interval (288.15K ? 313.15K) and limiting activity coefficient of Decane in Tetraglyme was subsequently obtained by extrapolation in a homologous line. LLE was measured by direct analytical and turbidity methods. Excess enthalpy and excess heat capacity data were collected from literature. The studied system shows upper critical solubility temperature and ?M-shape? of excess heat capacity concentration dependence and therefore high number of correlation equation parameters was needed for a precise description of temperature and concentration dependence of Gibbs excess energy and related physical properties. Properties related to vapor-liquid and liquid-liquid equilibria have been measured, collected from literature and subsequently simultaneously correlated using Redlich-Kister equation for the binary system Tetraglyme + Decane. IGS method was used for measurement of limiting activity coefficients of alkanes (C5-C8) in Tetraglyme in temperature interval (288.15K ? 313.15K) and limiting activity coefficient of Decane in Tetraglyme was subsequently obtained by extrapolation in a homologous line. LLE was measured by direct analytical and turbidity methods. Excess enthalpy and excess heat capacity data were collected from literature. The studied system shows upper critical solubility temperature and ?M-shape? of excess heat capacity concentration dependence and therefore high number of correlation equation parameters was needed for a precise description of temperature and concentration dependence of Gibbs excess energy and related physical properties. (en) Properties related to vapor-liquid and liquid-liquid equilibria have been measured, collected from literature and subsequently simultaneously correlated using Redlich-Kister equation for the binary system Tetraglyme + Decane. IGS method was used for measurement of limiting activity coefficients of alkanes (C5-C8) in Tetraglyme in temperature interval (288.15K ? 313.15K) and limiting activity coefficient of Decane in Tetraglyme was subsequently obtained by extrapolation in a homologous line. LLE was measured by direct analytical and turbidity methods. Excess enthalpy and excess heat capacity data were collected from literature. The studied system shows upper critical solubility temperature and ?M-shape? of excess heat capacity concentration dependence and therefore high number of correlation equation parameters was needed for a precise description of temperature and concentration dependence of Gibbs excess energy and related physical properties. (cs)
Title	Simultaneous correlation of VLE and LLE experimental data for system with upper critical solubility temperature (tetraglyme ? decane) Simultaneous correlation of VLE and LLE experimental data for system with upper critical solubility temperature (tetraglyme ? decane) (en) Simultánní korelace experimentálbích dat o rovnováze kapalina - pára a kapalina - kapalina pro systém s horní kritickou rozpouštěcí teplotou (tetraglym + dekan) (cs)
skos:prefLabel	Simultaneous correlation of VLE and LLE experimental data for system with upper critical solubility temperature (tetraglyme ? decane) Simultaneous correlation of VLE and LLE experimental data for system with upper critical solubility temperature (tetraglyme ? decane) (en) Simultánní korelace experimentálbích dat o rovnováze kapalina - pára a kapalina - kapalina pro systém s horní kritickou rozpouštěcí teplotou (tetraglym + dekan) (cs)
skos:notation	RIV/60461373:22340/08:00020686!RIV09-MSM-22340___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6046137307)
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Hovorka, Štěpán Řehák, Karel Bartovská, Lidmila
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	394935
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/08:00020686
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	vapor-liquid equilibrium; liquid-liquid equilibrium; tetraglyme; decane (en)
http://linked.open.../riv/klicoveSlovo	vapor-liquid equilibrium liquid-liquid equilibrium decane tetraglyme
http://linked.open...ontrolniKodProRIV	[887392C062C8]
http://linked.open...v/mistoKonaniAkce	Praha, Česká Republika
http://linked.open...i/riv/mistoVydani	Praha
http://linked.open...i/riv/nazevZdroje	CD-ROM of Full Texts CHISA 2008
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...iv/tvurceVysledku	Řehák, Karel Bartovská, Lidmila Hovorka, Štěpán Volejníková, Barbora
http://linked.open...vavai/riv/typAkce	WRD - Světová
http://linked.open.../riv/zahajeniAkce	2008-08-24 (xsd:date)
http://linked.open...n/vavai/riv/zamer	Physico-chemical methods of analysis and characterization of chemical systems and biosystems
number of pages	14 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Process Engineering Publisher
https://schema.org/isbn	978-80-02-02047-9
http://localhost/t...ganizacniJednotka	22340

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