About: Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate

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About: Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate Goto Sponge NotDistinct Permalink

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Two types of (acridin-9-yl)thiosemicarbazides with the acridine moiety in the thiourea part (Acr-NHCS, 10a, 10b) and hydrazine part (Acr-NHNHCS, 12a-12c) were prepared to investigate their reactions with dimethyl acetylenedicarboxylate. Five-membered thiazolidinone derivatives 15a, 15b, 19a-19c were formed; some aspects of corresponding reaction mechanisms are discussed. 1D and 2D 1H and 13C NMR spectroscopy and DFT quantum chemical calculations were used to elucidate the structure of the compounds. Two types of (acridin-9-yl)thiosemicarbazides with the acridine moiety in the thiourea part (Acr-NHCS, 10a, 10b) and hydrazine part (Acr-NHNHCS, 12a-12c) were prepared to investigate their reactions with dimethyl acetylenedicarboxylate. Five-membered thiazolidinone derivatives 15a, 15b, 19a-19c were formed; some aspects of corresponding reaction mechanisms are discussed. 1D and 2D 1H and 13C NMR spectroscopy and DFT quantum chemical calculations were used to elucidate the structure of the compounds. (en) Two types of (acridin-9-yl)thiosemicarbazides with the acridine moiety in the thiourea part (Acr-NHCS, 10a, 10b) and hydrazine part (Acr-NHNHCS, 12a-12c) were prepared to investigate their reactions with dimethyl acetylenedicarboxylate. Five-membered thiazolidinone derivatives 15a, 15b, 19a-19c were formed; some aspects of corresponding reaction mechanisms are discussed. 1D and 2D 1H and 13C NMR spectroscopy and DFT quantum chemical calculations were used to elucidate the structure of the compounds. (cs)
Title	Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate (en) Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate (cs)
skos:prefLabel	Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate (en) Heterocyclization of (Acridin-9-yl)Thiosemicarbazides with Dimethyl Acetylenedicarboxylate (cs)
skos:notation	RIV/60461373:22340/07:00019323!RIV08-MSM-22340___
http://linked.open.../vavai/riv/strany	347-362
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6046137301)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Böhm, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	424027
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/07:00019323
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Thiosemicarbazides; Thiazolidinones; Acridines; Acetylenedicarboxylate; Quantum chemical calculations; Reaction mechanisms. (en)
http://linked.open.../riv/klicoveSlovo	Quantum chemical calculations Acridines Thiosemicarbazides Acetylenedicarboxylate Reaction mechanisms. Thiazolidinones
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[B91058A5AD2F]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	72
http://linked.open...iv/tvurceVysledku	Böhm, Stanislav Imrich, Jan Kristian, Pavol Danihel, Ivan Tomaščiková, Jana
http://linked.open...n/vavai/riv/zamer	Catalytic processes in chemistry and chemical technology
issn	0010-0765
number of pages	16 (xsd:int)
http://localhost/t...ganizacniJednotka	22340

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