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Description
  • Stationary and non-stationary behavior of an electrolyte diode system is studied. The system consists of a microcapillary connecting two reservoirs with a strong acid and strong base. If an external electric field is imposed on the capillary, diode like current-voltage characteristics is observed. A thin layer of electrolyte with extremely large pH gradient is formed in the closed regime of the diode. Transient behavior of the electrolyte diode is studied experimentally and numerically. Observed short-time overshoots of electric current in the current-voltage characteristics are explained based on numerical analysis of the reaction-transport processes in the capillary.
  • Stationary and non-stationary behavior of an electrolyte diode system is studied. The system consists of a microcapillary connecting two reservoirs with a strong acid and strong base. If an external electric field is imposed on the capillary, diode like current-voltage characteristics is observed. A thin layer of electrolyte with extremely large pH gradient is formed in the closed regime of the diode. Transient behavior of the electrolyte diode is studied experimentally and numerically. Observed short-time overshoots of electric current in the current-voltage characteristics are explained based on numerical analysis of the reaction-transport processes in the capillary. (en)
  • Stacionární a nestacionární chování elektrolytické diody bylo studováno. Byly vytvořeny voltampérové charakteristiky. Experimentálně pozorované krátkodobé překmity elektrického proudu během některých transientů jsou vysvětleny pomocí numerické analýzy studovaného systému. (cs)
Title
  • Dynamical and stationary analysis of an electrolyte diode and comparison with experiments
  • Dynamická a stacionární analýza elektrolytické diody a porovnání s experimenty (cs)
  • Dynamical and stationary analysis of an electrolyte diode and comparison with experiments (en)
skos:prefLabel
  • Dynamical and stationary analysis of an electrolyte diode and comparison with experiments
  • Dynamická a stacionární analýza elektrolytické diody a porovnání s experimenty (cs)
  • Dynamical and stationary analysis of an electrolyte diode and comparison with experiments (en)
skos:notation
  • RIV/60461373:22340/06:00016653!RIV07-MSM-22340___
http://linked.open.../vavai/riv/strany
  • 291-296
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/04/1442), Z(MSM6046137306)
http://linked.open...iv/cisloPeriodika
  • A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 472623
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/06:00016653
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http://linked.open.../riv/klicovaSlova
  • electrolyte diode; electrophoresis; microchip; transients; mathematical modeling (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [B3E0E0691CEE]
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  • Computer-Aided Chemical Engineering
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 21
http://linked.open...iv/tvurceVysledku
  • Slouka, Zdeněk
  • Šnita, Dalimil
  • Přibyl, Michal
  • Lindner, Jiří
  • Marek, Miloš
http://linked.open...n/vavai/riv/zamer
issn
  • 1570-7946
number of pages
http://localhost/t...ganizacniJednotka
  • 22340
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