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| Description
| - While the most catalysts applying for mimicking of oxygenation function of cytochrome P450 rely on the metalloporphyrins, we present here novel approach based on Mn+ metallocomplexes of novel ligands: arylmethyl substituted bis--aminoketones. The efficacy of catalyst for 1-hexene oxygenation was tested as function of Mn+, ligand type and reaction conditions. Our results revealed that the best performance is for Co(II) metallocomplexes of ligand N,N'-ethylenebis[4-amino-1,5-di-(2-naphthyl)]pent-3-en-2-one are the most efficient for conversion of 1-hexene to oxygenation products. Analysis of product distribution was performed with GC-MS analysis, the mild conditions of analysis allowed to detect primary products of oxygenation reaction
- While the most catalysts applying for mimicking of oxygenation function of cytochrome P450 rely on the metalloporphyrins, we present here novel approach based on Mn+ metallocomplexes of novel ligands: arylmethyl substituted bis--aminoketones. The efficacy of catalyst for 1-hexene oxygenation was tested as function of Mn+, ligand type and reaction conditions. Our results revealed that the best performance is for Co(II) metallocomplexes of ligand N,N'-ethylenebis[4-amino-1,5-di-(2-naphthyl)]pent-3-en-2-one are the most efficient for conversion of 1-hexene to oxygenation products. Analysis of product distribution was performed with GC-MS analysis, the mild conditions of analysis allowed to detect primary products of oxygenation reaction (en)
- Zatímco většina katalyzátorů používaných pro modelování oxygenační funkce cytochromu P450 je založena na metalloporfyrinech, představujeme nový přístup založený na Mn+ metallokomplexech nových ligandů: arylmethyl substituovaných bis-beta-aminoketonů. Účinnost katalyzátorů při oxidaci 1-hexenu byla testována jako funkce Mn+, typu ligandu a reakčních podmínek. Výsledky ukázaly nejlepší účinek Co(II) metallokomplexu ligandu N,N'-ethylenebis[4-amino-1,5-di-(2-naphthyl)]pent-3-en-2-on pro konverzi 1-hexenu na xidační produkty. Analýza distribuce produktů byla prováděna GC-MS analýzou, mírné podmínky analýzy umožnily detekovat primární produkty exidační reakce (cs)
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| Title
| - Aplikace nových metallokomplexů pro napodobení cytochromu P450 - Analýzy distribuce produktu pro 1-hexen jako substrát (cs)
- Application of novel metallocomplexes for mimicking of cytochrome P450 - Analysis of product distribution for 1-hexene as a substrate
- Application of novel metallocomplexes for mimicking of cytochrome P450 - Analysis of product distribution for 1-hexene as a substrate (en)
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| skos:prefLabel
| - Aplikace nových metallokomplexů pro napodobení cytochromu P450 - Analýzy distribuce produktu pro 1-hexen jako substrát (cs)
- Application of novel metallocomplexes for mimicking of cytochrome P450 - Analysis of product distribution for 1-hexene as a substrate
- Application of novel metallocomplexes for mimicking of cytochrome P450 - Analysis of product distribution for 1-hexene as a substrate (en)
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| skos:notation
| - RIV/60461373:22340/04:00011218!RIV08-MSM-22340___
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(GA203/02/0933), R, Z(MSM 223400008)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22340/04:00011218
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - Cytochrome P450; Enzyme mimick; Oxygenation; Metallocomplexes; Product distribution (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Molecular Catalysis
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Král, Vladimír
- Zachař, Pavel
- Borek, Vojtěch
- Laatikainen, R.
- Pulkkinen, J.
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| http://localhost/t...ganizacniJednotka
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