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  • Aqueous electrolyte systems can exhibit complex behaviour, e. g., nonlinear coupling between potential difference and electric current, bistability, oscillations and signal amplification. Mass and momentum balances together with Gauss law of electrostatics are given and transformed into dimensionless forms. The commercial software FEMLAB has been used for numerical solutions of the set of partial differential equations describing 2D model of nanochannel which is filled by uni-uni-valent electrolyte and exposed to an external electric field, in which diffusion, migration and electroosmotically driven convection take place. We consider that negative electric charge is fixed on solid surface. Examples of nonlinear coupling between potential difference andelectric current are discussed.
  • Aqueous electrolyte systems can exhibit complex behaviour, e. g., nonlinear coupling between potential difference and electric current, bistability, oscillations and signal amplification. Mass and momentum balances together with Gauss law of electrostatics are given and transformed into dimensionless forms. The commercial software FEMLAB has been used for numerical solutions of the set of partial differential equations describing 2D model of nanochannel which is filled by uni-uni-valent electrolyte and exposed to an external electric field, in which diffusion, migration and electroosmotically driven convection take place. We consider that negative electric charge is fixed on solid surface. Examples of nonlinear coupling between potential difference andelectric current are discussed. (en)
Title
  • Nonlinear behavior of simple ionic microsystems. Mathematical modeling and experiments
  • Nonlinear behavior of simple ionic microsystems. Mathematical modeling and experiments (en)
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  • Nonlinear behavior of simple ionic microsystems. Mathematical modeling and experiments
  • Nonlinear behavior of simple ionic microsystems. Mathematical modeling and experiments (en)
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  • RIV/60461373:22340/03:00007663!RIV/2004/GA0/223404/N
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  • R 6 (1-9)
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  • P(GA104/02/0339)
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  • 618120
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  • RIV/60461373:22340/03:00007663
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  • electroosmosis; nanochannel; microchannel;FEMLAB (en)
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  • [02D1C7F54150]
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  • Tatranské Matliare, Slovakia
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  • Bratislava
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  • Proceedings of the 30th International Conference of Slovak Society of Chemical Engineering, Tatranské Matliare 26.- 30.5.2003, CD-ROM
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  • Šnita, Dalimil
  • Marek, Miloš
  • Postler, Tomáš
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number of pages
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  • Slovenská technická univerzita v Bratislave
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  • 80-227-1889-0
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  • 22340
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