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Description
| - Mathematical modeling approach for open-tubular capillary electrochromatography is presented. The spatially one-dimensional model takes into account (i) a coupling of (non)linear adsorption of positively or negatively charged analyte molecules (at a negatively charged capillary inner surface) with the equilibrium electrokinetics at this solid-liquid interface, (ii) mobile phase transport by electroosmosis and pressuredriven flow, as well as (iii) transport of species by electrophoresis and molecular diffusion. The resulting inhomogeneity of electroosmotic flow through the capillary produces a compensating pore pressure as requirement for incompressible mobile phase flow.
- Mathematical modeling approach for open-tubular capillary electrochromatography is presented. The spatially one-dimensional model takes into account (i) a coupling of (non)linear adsorption of positively or negatively charged analyte molecules (at a negatively charged capillary inner surface) with the equilibrium electrokinetics at this solid-liquid interface, (ii) mobile phase transport by electroosmosis and pressuredriven flow, as well as (iii) transport of species by electrophoresis and molecular diffusion. The resulting inhomogeneity of electroosmotic flow through the capillary produces a compensating pore pressure as requirement for incompressible mobile phase flow. (en)
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Title
| - Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry,
- Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, (en)
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skos:prefLabel
| - Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry,
- Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, (en)
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skos:notation
| - RIV/60461373:22340/03:00007661!RIV/2004/GA0/223404/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA104/02/0339), Z(MSM 223400007)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22340/03:00007661
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - capillary electrochromatography; adsroption; electric double layer; electroosmosis; electrophoresis (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Kosek, Juraj
- Marek, Miloš
- Pačes, Martin
- Seidel-Morgensetern, A.
- Tallarek, U.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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