About: Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry,

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About: Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Mathematical modeling approach for open-tubular capillary electrochromatography is presented. The spatially one-dimensional model takes into account (i) a coupling of (non)linear adsorption of positively or negatively charged analyte molecules (at a negatively charged capillary inner surface) with the equilibrium electrokinetics at this solid-liquid interface, (ii) mobile phase transport by electroosmosis and pressuredriven flow, as well as (iii) transport of species by electrophoresis and molecular diffusion. The resulting inhomogeneity of electroosmotic flow through the capillary produces a compensating pore pressure as requirement for incompressible mobile phase flow. Mathematical modeling approach for open-tubular capillary electrochromatography is presented. The spatially one-dimensional model takes into account (i) a coupling of (non)linear adsorption of positively or negatively charged analyte molecules (at a negatively charged capillary inner surface) with the equilibrium electrokinetics at this solid-liquid interface, (ii) mobile phase transport by electroosmosis and pressuredriven flow, as well as (iii) transport of species by electrophoresis and molecular diffusion. The resulting inhomogeneity of electroosmotic flow through the capillary produces a compensating pore pressure as requirement for incompressible mobile phase flow. (en)
Title	Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, (en)
skos:prefLabel	Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, Mathematical modelling of adsorption and transport processes in capillary electrochromatography: Open-tubular geometry, (en)
skos:notation	RIV/60461373:22340/03:00007661!RIV/2004/GA0/223404/N
http://linked.open.../vavai/riv/strany	380-389
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/02/0339), Z(MSM 223400007)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Kosek, Juraj Marek, Miloš Pačes, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	614497
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/03:00007661
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	capillary electrochromatography; adsroption; electric double layer; electroosmosis; electrophoresis (en)
http://linked.open.../riv/klicoveSlovo	electric double layer electrophoresis capillary electrochromatography electroosmosis adsroption
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[7BE589141B8A]
http://linked.open...i/riv/nazevZdroje	Electrophoresis
http://linked.open...in/vavai/riv/obor	CI
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Nonstationary operation of microreactors
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	24
http://linked.open...iv/tvurceVysledku	Kosek, Juraj Marek, Miloš Pačes, Martin Seidel-Morgensetern, A. Tallarek, U.
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223400007
issn	0173-0835
number of pages	10 (xsd:int)
http://localhost/t...ganizacniJednotka	22340

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