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  • The main aim of this work is the application of various models describing the transport of a penetrant during pervaporation process in the membrane and their comparison.We experimentally determined sorption isotherms of pure components, diffusion coefficients, non-ideal sorption of liquid binary mixture in a membrane and the density of the membrane versus concentration composition. All mentioned dependencies were mathematically described and then introduced into a Flory-Rehner equations, UNIFAP model and modified Maxwell-Stefan equations. Models were used for description of the transport of liquid binary mixtures (pentan-1-ol, hexan-1-ol with toluene) through the low-density polyethylene membrane at 25 °C. Calculated pervaporation fluxes and separationdiagrams were compared with the results of the experiments.
  • The main aim of this work is the application of various models describing the transport of a penetrant during pervaporation process in the membrane and their comparison.We experimentally determined sorption isotherms of pure components, diffusion coefficients, non-ideal sorption of liquid binary mixture in a membrane and the density of the membrane versus concentration composition. All mentioned dependencies were mathematically described and then introduced into a Flory-Rehner equations, UNIFAP model and modified Maxwell-Stefan equations. Models were used for description of the transport of liquid binary mixtures (pentan-1-ol, hexan-1-ol with toluene) through the low-density polyethylene membrane at 25 °C. Calculated pervaporation fluxes and separationdiagrams were compared with the results of the experiments. (en)
Title
  • Comparison of various models for transport of binary mixtures through dense polymer membrane
  • Comparison of various models for transport of binary mixtures through dense polymer membrane (en)
skos:prefLabel
  • Comparison of various models for transport of binary mixtures through dense polymer membrane
  • Comparison of various models for transport of binary mixtures through dense polymer membrane (en)
skos:notation
  • RIV/60461373:22340/03:00007434!RIV/2004/GA0/223404/N
http://linked.open.../vavai/riv/strany
  • 2679-2687
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/01/0945), Z(AV0Z4072921), Z(MSM 223400008)
http://linked.open...iv/cisloPeriodika
  • 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 601806
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/03:00007434
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Modified Maxwell-Stefan equations; Flory-Rehner equations; UNIFAP model; (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [044A4B43B185]
http://linked.open...i/riv/nazevZdroje
  • Polymer
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 44
http://linked.open...iv/tvurceVysledku
  • Izák, Pavel
  • Friess, Karel
  • Šípek, Milan
  • Uchytil, Petr
  • Bartovská, Lidmila
http://linked.open...n/vavai/riv/zamer
issn
  • 0032-3861
number of pages
http://localhost/t...ganizacniJednotka
  • 22340
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