About: (Vapour + liquid) equilibria and excess molar enthalpies for mixtures with strong complex formation. Trichloromethane or 1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) with tetrahydropyran or piperidine     Goto   Sponge   NotDistinct   Permalink

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  • Isothermal vapour + liquid equilibria were measured for {trichloromethane + tetrahydropyran or piperidine} at 333.15 K and {1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) + tetrahydropyran or piperidine} at 323.15 K using a circulation still. The results were verified by effective statistical procedures and used to calculate activity coefficients and excess molar Gibbs free energies. Excess molar enthalpies for these mixtures were determined at 298.15 K by means of an isothermal CSC microcalorimeterequipped with recently reconstructed flow mixing cells. Reliable performance of the calorimetric setup was proved by measurements of excess molar enthalpies for (hexane + cyclohexane), (2-propanone + water) and (methanol + water) comparing the results w ith best literature data. The trichloromethane or halothane containing mixtures exhibit strong negative deviations from Raoult's law and are highly exothermic, thus indicating that the complex formation via hydrogen bonding is a governing non-ideality ef
  • Isothermal vapour + liquid equilibria were measured for {trichloromethane + tetrahydropyran or piperidine} at 333.15 K and {1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) + tetrahydropyran or piperidine} at 323.15 K using a circulation still. The results were verified by effective statistical procedures and used to calculate activity coefficients and excess molar Gibbs free energies. Excess molar enthalpies for these mixtures were determined at 298.15 K by means of an isothermal CSC microcalorimeterequipped with recently reconstructed flow mixing cells. Reliable performance of the calorimetric setup was proved by measurements of excess molar enthalpies for (hexane + cyclohexane), (2-propanone + water) and (methanol + water) comparing the results w ith best literature data. The trichloromethane or halothane containing mixtures exhibit strong negative deviations from Raoult's law and are highly exothermic, thus indicating that the complex formation via hydrogen bonding is a governing non-ideality ef (en)
Title
  • (Vapour + liquid) equilibria and excess molar enthalpies for mixtures with strong complex formation. Trichloromethane or 1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) with tetrahydropyran or piperidine
  • (Vapour + liquid) equilibria and excess molar enthalpies for mixtures with strong complex formation. Trichloromethane or 1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) with tetrahydropyran or piperidine (en)
skos:prefLabel
  • (Vapour + liquid) equilibria and excess molar enthalpies for mixtures with strong complex formation. Trichloromethane or 1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) with tetrahydropyran or piperidine
  • (Vapour + liquid) equilibria and excess molar enthalpies for mixtures with strong complex formation. Trichloromethane or 1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) with tetrahydropyran or piperidine (en)
skos:notation
  • RIV/60461373:22340/02:00006959!RIV/2004/MSM/223404/N
http://linked.open.../vavai/riv/strany
  • 361-376
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ME 237), Z(MSM 223400008)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 668396
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/02:00006959
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Vapour liquid equilibria; excess enthalpy; strong komplex formation; halothane; trichloromethane; (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [10D1B7421859]
http://linked.open...i/riv/nazevZdroje
  • The Journal of Chemical Thermodynamics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 34
http://linked.open...iv/tvurceVysledku
  • Dohnal, Vladimír
  • Řehák, Karel
  • Vrbka, Pavel
  • Fenclová, Dana
  • García-Miaja, Gonzalo
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9614
number of pages
http://localhost/t...ganizacniJednotka
  • 22340
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