About: Intercalates of Vanadyl Phosphate with Unsaturated Alcohols

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Intercalates of VOPO4 with several linear unsaturated alcohols (2-propen-1-ol, 2-buten-1-ol, 2-propyn-1-ol, 2-butyn-1-ol, 3-butyn-1-ol 2-pentyn-1-ol, 3-pentyn-1-ol, 4-pentyn-1-ol, 5-hexyn-1-ol, 2-octyn-1-ol, and 10-undecyn-1-ol) have been prepared and characterized by powder X-ray diffractometry, IR and Raman spectrometry, and thermogravimetry. The arrangement of the alcohol molecules with respect to the type and position of the multiple bonds in the carbon chain is proposed. Alcohols with terminal triple bonds form very stable intercalates. It is presumed that these alcohols are anchored to the host layers by donor-acceptor bonds between their oxygen atoms and the vanadium atoms of the host, and by H-bonding between the acetylenic hydrogen of the terminal carbon and the oxygen atoms of the host. Intercalates of VOPO4 with several linear unsaturated alcohols (2-propen-1-ol, 2-buten-1-ol, 2-propyn-1-ol, 2-butyn-1-ol, 3-butyn-1-ol 2-pentyn-1-ol, 3-pentyn-1-ol, 4-pentyn-1-ol, 5-hexyn-1-ol, 2-octyn-1-ol, and 10-undecyn-1-ol) have been prepared and characterized by powder X-ray diffractometry, IR and Raman spectrometry, and thermogravimetry. The arrangement of the alcohol molecules with respect to the type and position of the multiple bonds in the carbon chain is proposed. Alcohols with terminal triple bonds form very stable intercalates. It is presumed that these alcohols are anchored to the host layers by donor-acceptor bonds between their oxygen atoms and the vanadium atoms of the host, and by H-bonding between the acetylenic hydrogen of the terminal carbon and the oxygen atoms of the host. (en)
Title	Intercalates of Vanadyl Phosphate with Unsaturated Alcohols Intercalates of Vanadyl Phosphate with Unsaturated Alcohols (en)
skos:prefLabel	Intercalates of Vanadyl Phosphate with Unsaturated Alcohols Intercalates of Vanadyl Phosphate with Unsaturated Alcohols (en)
skos:notation	RIV/60461373:22340/01:00004916!RIV/2004/MSM/223404/N
http://linked.open.../vavai/riv/strany	713;719
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 223400008)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Matějka, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	683265
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/01:00004916
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Vanadium; Phosphorus; Alcohols; Intercalations; Vibrational spectroscopy; X-ray scattering (en)
http://linked.open.../riv/klicoveSlovo	Alcohols X-ray scattering Phosphorus Vanadium Intercalations Vibrational spectroscopy
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[FC5A22B74732]
http://linked.open...i/riv/nazevZdroje	European Journal of Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	Neuveden
http://linked.open...iv/tvurceVysledku	Matějka, Pavel Beneš, L. Trchová, M. Zima, V. Uhlířová, E. Melánová, K.
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223400008
issn	1438-1948
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	22340

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