About: Rapid monitoring of heat-accelerated reactions in vegetable oils using direct analysis in real time ionization coupled with high resolution mass spectrometry     Goto   Sponge   NotDistinct   Permalink

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Description
  • Transmission-mode direct analysis in real time ionization coupled with high resolution mass spektrometry (TM-DART?HRMS) was used to monitor chemical changes in various vegetable oils (olive, rapeseed, soybean and sunflower oil) during their thermally-induced oxidation. This novel instrumental approach enabled rapid fingerprinting of examined samples and detection of numerous sample components, such as triacylglycerols (TAGs), phytosterols, free fatty acids (FFA), and their respective oxidation products. Mass spectra obtained from DART were processed with the use of principal component analysis (PCA) in order to assess the compositional differences between heated and non-heated samples. Good correlation was observed between the normalized intensities of the pre-selected ion corresponding to monooxidized TAG and ?classic? criterion represented by the levels of TAG polymers determined by high performance-size exclusion chromatography with refractometric detection (HP-SEC?RID).
  • Transmission-mode direct analysis in real time ionization coupled with high resolution mass spektrometry (TM-DART?HRMS) was used to monitor chemical changes in various vegetable oils (olive, rapeseed, soybean and sunflower oil) during their thermally-induced oxidation. This novel instrumental approach enabled rapid fingerprinting of examined samples and detection of numerous sample components, such as triacylglycerols (TAGs), phytosterols, free fatty acids (FFA), and their respective oxidation products. Mass spectra obtained from DART were processed with the use of principal component analysis (PCA) in order to assess the compositional differences between heated and non-heated samples. Good correlation was observed between the normalized intensities of the pre-selected ion corresponding to monooxidized TAG and ?classic? criterion represented by the levels of TAG polymers determined by high performance-size exclusion chromatography with refractometric detection (HP-SEC?RID). (en)
Title
  • Rapid monitoring of heat-accelerated reactions in vegetable oils using direct analysis in real time ionization coupled with high resolution mass spectrometry
  • Rapid monitoring of heat-accelerated reactions in vegetable oils using direct analysis in real time ionization coupled with high resolution mass spectrometry (en)
skos:prefLabel
  • Rapid monitoring of heat-accelerated reactions in vegetable oils using direct analysis in real time ionization coupled with high resolution mass spectrometry
  • Rapid monitoring of heat-accelerated reactions in vegetable oils using direct analysis in real time ionization coupled with high resolution mass spectrometry (en)
skos:notation
  • RIV/60461373:22330/13:43896493!RIV14-MSM-22330___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6046137305)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 101486
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22330/13:43896493
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Mass spectrometry; direct analysis in real time; Heating; Oxidation; Vegetable oils (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • BE - Belgické království
http://linked.open...ontrolniKodProRIV
  • [79472B3C876F]
http://linked.open...i/riv/nazevZdroje
  • Food Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 138
http://linked.open...iv/tvurceVysledku
  • Bělková, Beverly
  • Hajšlová, Jana
  • Riddellová, Kateřina
  • Réblová, Zuzana
  • Václavík, Lukáš
http://linked.open...ain/vavai/riv/wos
  • 000317159900032
http://linked.open...n/vavai/riv/zamer
issn
  • 0308-8146
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.foodchem.2012.12.019
http://localhost/t...ganizacniJednotka
  • 22330
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