About: Synthesis and Mass Spectral Fragmentation Patterns of Brassinolide Early Biosynthetic Precursors Labeled at C-26

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About: Synthesis and Mass Spectral Fragmentation Patterns of Brassinolide Early Biosynthetic Precursors Labeled at C-26 Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	New analogues of brassinolide biosynthetic precursors with three deuterium atoms at non-exchangeable positions have been synthesized to be used as standards for quantification of natural brassinosteroids by liquid chromatography-mass spectrometry. [26-H-2(3)](22R,23R,24S)-22,23-Dihydroxy-6 beta-methoxy-24-methyl-3 alpha,5-cyclo-5 alpha-cholestane was used as a starting material for the preparation of campestane derivatives having a 22R,23R-diol functionality and either a hydroxy or keto group at C-3 and labeled at C-26. The mass spectrometric behavior of the newly synthesized compounds has been studied. New analogues of brassinolide biosynthetic precursors with three deuterium atoms at non-exchangeable positions have been synthesized to be used as standards for quantification of natural brassinosteroids by liquid chromatography-mass spectrometry. [26-H-2(3)](22R,23R,24S)-22,23-Dihydroxy-6 beta-methoxy-24-methyl-3 alpha,5-cyclo-5 alpha-cholestane was used as a starting material for the preparation of campestane derivatives having a 22R,23R-diol functionality and either a hydroxy or keto group at C-3 and labeled at C-26. The mass spectrometric behavior of the newly synthesized compounds has been studied. (en)
Title	Synthesis and Mass Spectral Fragmentation Patterns of Brassinolide Early Biosynthetic Precursors Labeled at C-26 Synthesis and Mass Spectral Fragmentation Patterns of Brassinolide Early Biosynthetic Precursors Labeled at C-26 (en)
skos:prefLabel	Synthesis and Mass Spectral Fragmentation Patterns of Brassinolide Early Biosynthetic Precursors Labeled at C-26 Synthesis and Mass Spectral Fragmentation Patterns of Brassinolide Early Biosynthetic Precursors Labeled at C-26 (en)
skos:notation	RIV/60461373:22330/13:43895398!RIV14-MSM-22330___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ED0007/01/01), P(IAA400550801), Z(AV0Z50380511), Z(MSM6046137305)
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Drašar, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta potravinářské a biochemické technologie
http://linked.open...dnocenehoVysledku	109485
http://linked.open...ai/riv/idVysledku	RIV/60461373:22330/13:43895398
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Mass spectrometry; Isotope labeling; 3-Dehydro-6-deoxoteasterone; 6-Deoxoteasterone; Biosynthesis; Brassinolide; Brassinosteroids (en)
http://linked.open.../riv/klicoveSlovo	Biosynthesis 3-Dehydro-6-deoxoteasterone 6-Deoxoteasterone Isotope labeling Mass spectrometry Brassinolide Brassinosteroids
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[C5A4227D3750]
http://linked.open...i/riv/nazevZdroje	NATURAL PRODUCT COMMUNICATIONS
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Synthesis of tritium labelled brassinosteroids and their application in the studies of their mechanism of action on molecular level. Centre of the Region Haná for Biotechnological and Agricultural Research
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	8
http://linked.open...iv/tvurceVysledku	Strnad, Miroslav Tarkowská, Danuše Drašar, Pavel Khripach, Vladimir A. Zhabinskii, Vladimir N. Ermolovich, Yurii V. Gulyakevich, Olga V.
http://linked.open...ain/vavai/riv/wos	000319855300024
http://linked.open...n/vavai/riv/zamer	Mechanismy regulace růstu a vývoje rostlin na úrovni buněk, orgánů a celých organismů: fyziologické, genetické a molekulárně biologické základy Teoretické základy potravinářských a biochemických technologií
issn	1934-578X
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	22330

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