About: An engineering analysis of alkali hydrolysis of 2,4,6-trinitrotoluene

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Alkali hydrolysis of TNT was studied at two temperatures (isothermal operation) and in several experiments where temperature was not controlled. The experimental data were used to determine the overall stoichiometry of TNT and hydroxyl ions, and to develop a simple kinetic model. A TNT-independent sink for hydroxyl ions accounts for system-specific loss of hydroxyl ions in control reactions. Activation energies of the individual reactions were estimated and the kinetic model was used to predict the experimental data in experiments. The experimental data and the kinetic model have been presented in this paper. Alkali hydrolysis of TNT was studied at two temperatures (isothermal operation) and in several experiments where temperature was not controlled. The experimental data were used to determine the overall stoichiometry of TNT and hydroxyl ions, and to develop a simple kinetic model. A TNT-independent sink for hydroxyl ions accounts for system-specific loss of hydroxyl ions in control reactions. Activation energies of the individual reactions were estimated and the kinetic model was used to predict the experimental data in experiments. The experimental data and the kinetic model have been presented in this paper. (en)
Title	An engineering analysis of alkali hydrolysis of 2,4,6-trinitrotoluene An engineering analysis of alkali hydrolysis of 2,4,6-trinitrotoluene (en)
skos:prefLabel	An engineering analysis of alkali hydrolysis of 2,4,6-trinitrotoluene An engineering analysis of alkali hydrolysis of 2,4,6-trinitrotoluene (en)
skos:notation	RIV/60461373:22330/02:00007291!RIV/2004/GA0/223304/N
http://linked.open.../vavai/riv/strany	N
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA104/01/0458)
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Páca, Jan
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta potravinářské a biochemické technologie
http://linked.open...dnocenehoVysledku	637968
http://linked.open...ai/riv/idVysledku	RIV/60461373:22330/02:00007291
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	kinetics, mathematical model, TNT, activation energy, rate expression, simulation (en)
http://linked.open.../riv/klicoveSlovo	activation energy kinetics mathematical model simulation TNT rate expression
http://linked.open...ontrolniKodProRIV	[4B4664DF0F7F]
http://linked.open...v/mistoKonaniAkce	Praha
http://linked.open...i/riv/mistoVydani	Prague
http://linked.open...i/riv/nazevZdroje	15th International Congress of Chemical and Process Engineering CHISA 2002CD-ROM
http://linked.open...in/vavai/riv/obor	EI
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Microbial mineralization of nitroaromatics
http://linked.open...UplatneniVysledku	2002
http://linked.open...iv/tvurceVysledku	Páca, Jan Bajpai, Rakesh Herman, Sylvester Parekh, Daniel Popovic, Milan
http://linked.open...vavai/riv/typAkce	CST - Celostátní
http://linked.open.../riv/zahajeniAkce	2002-08-25 (xsd:date)
number of pages	2 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Process Engineering Publisher
https://schema.org/isbn	80-86059-33-2
http://localhost/t...ganizacniJednotka	22330

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