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Description
  • Thiophene- and furan-derived aminocarbene complexes are regioselectively lithiated by BuLi at position 5, while lithiated aminocarbenes containing pyrrole or phenyl groups can be obtained by a bromine to lithium exchange reaction using BuLi. Such prepared lithiated aminocarbene complexes react with alkyl halides, aldehydes, ketones, acyl chlorides, and DMF, giving high yields of functionalized aminocarbene complexes hardly accessible by other ways.
  • Thiophene- and furan-derived aminocarbene complexes are regioselectively lithiated by BuLi at position 5, while lithiated aminocarbenes containing pyrrole or phenyl groups can be obtained by a bromine to lithium exchange reaction using BuLi. Such prepared lithiated aminocarbene complexes react with alkyl halides, aldehydes, ketones, acyl chlorides, and DMF, giving high yields of functionalized aminocarbene complexes hardly accessible by other ways. (en)
Title
  • Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.
  • Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes. (en)
skos:prefLabel
  • Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.
  • Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes. (en)
skos:notation
  • RIV/60461373:22310/14:43898138!RIV15-MSM-22310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LC06070)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 26380
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/14:43898138
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ALKYNES; DIANION; DERIVATIVES; (AMINOCARBENE)CHROMIUM(0) COMPLEXES; ORGANIC-SYNTHESIS; DIASTEREOSELECTIVE CYCLOPROPANATION; ELECTRON-DEFICIENT ALKENES; FISCHER CARBENE COMPLEXES (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [62D3A9914C4C]
http://linked.open...i/riv/nazevZdroje
  • Organometallics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 33
http://linked.open...iv/tvurceVysledku
  • Váňová, Hana
  • Dvořák, Dalimil
  • Tobrman, Tomáš
  • Jurásková, Ivana
http://linked.open...ain/vavai/riv/wos
  • 000337936800007
issn
  • 0276-7333
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/om500182p
http://localhost/t...ganizacniJednotka
  • 22310
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