About: Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation

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About: Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A new type of calixarene-based receptor designed for the recognition of chiral anions was prepared by the introduction of (S)-2-methylbutan-1-ol moieties into the lower rim of calixarene. The immobilization of calixarene skeleton in the 1,3-alternate conformation enabled the construction of a cavity consisting of preorganised ureido functions and chiral substituents in close proximity. This cavity is capable of chiral discrimination of selected anions as demonstrated on d- and l-phenylalaninates. A new type of calixarene-based receptor designed for the recognition of chiral anions was prepared by the introduction of (S)-2-methylbutan-1-ol moieties into the lower rim of calixarene. The immobilization of calixarene skeleton in the 1,3-alternate conformation enabled the construction of a cavity consisting of preorganised ureido functions and chiral substituents in close proximity. This cavity is capable of chiral discrimination of selected anions as demonstrated on d- and l-phenylalaninates. (en)
Title	Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation (en)
skos:prefLabel	Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation (en)
skos:notation	RIV/60461373:22310/14:43898101!RIV15-GA0-22310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA13-21704S), P(IAAX08240901)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Botha, Filip Budka, Jan Lhoták, Pavel Eigner, Václav Hudeček, Oldřich
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	41602
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/14:43898101
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Anion recognition; Chiral receptor; NMR titration; Alkylation; Calixarene (en)
http://linked.open.../riv/klicoveSlovo	Anion recognition Calixarene NMR titration Alkylation Chiral receptor
http://linked.open...odStatuVydavatele	IE - Irsko
http://linked.open...ontrolniKodProRIV	[41930B453CD0]
http://linked.open...i/riv/nazevZdroje	Tetrahedron
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Electrochemically active calix[4]arenes and their use for preparation of new receptors and (bio)sensors Novel inorganic-organic hybrid nanomaterials
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	70
http://linked.open...iv/tvurceVysledku	Budka, Jan Císařová, Ivana Lhoták, Pavel Eigner, Václav Hudeček, Oldřich Vrzal, Lukáš Botha, Filip
http://linked.open...ain/vavai/riv/wos	000330816000043
issn	0040-4020
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.tet.2013.11.030
http://localhost/t...ganizacniJednotka	22310

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