About: The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1016/j.tetasy.2014.08.011
Description	Only four types of dimeric precursors [RuCl2(éta6-arene)]2 for the synthesis of Noyori's half sandwich diamine catalysts [RuCl(TsDPEN)(éta6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems perform during the asymmetric transfer hydrogenation of various 3,4-dihydroisoquinolines (i.e., the typical substrates for Noyori asymmetric transfer hydrogenation benchmarking). Experiments combined with molecular modeling allowed us to assess their properties and formulate a hypothesis clarifying the difference in enantioselectivity of these systems. Only four types of dimeric precursors [RuCl2(éta6-arene)]2 for the synthesis of Noyori's half sandwich diamine catalysts [RuCl(TsDPEN)(éta6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems perform during the asymmetric transfer hydrogenation of various 3,4-dihydroisoquinolines (i.e., the typical substrates for Noyori asymmetric transfer hydrogenation benchmarking). Experiments combined with molecular modeling allowed us to assess their properties and formulate a hypothesis clarifying the difference in enantioselectivity of these systems. (en)
Title	The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts (en)
skos:prefLabel	The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts (en)
skos:notation	RIV/60461373:22310/14:43897968!RIV15-GA0-22310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GAP106/12/1276)
http://linked.open...iv/cisloPeriodika	18-19
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Kačer, Petr Václavík, Jiří Pecháček, Jan Šot, Petr Vilhanová, Beáta
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	43197
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/14:43897968
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	arene; imines; ruthenium (en)
http://linked.open.../riv/klicoveSlovo	imines ruthenium arene
http://linked.open...odStatuVydavatele	IE - Irsko
http://linked.open...ontrolniKodProRIV	[7DF235B92537]
http://linked.open...i/riv/nazevZdroje	Tetrahedron Asymmetry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Asymmetric transfer hydrogenation of C=X bond: novel chiral auxiliaries, mechanistic studies and green catalyst heterogenization
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	25
http://linked.open...iv/tvurceVysledku	Kačer, Petr Kuzma, Marek Václavík, Jiří Vilhanová, Beáta Pecháček, Jan Zápal, Jakub Šot, Petr
http://linked.open...ain/vavai/riv/wos	000343847700014
issn	0957-4166
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.tetasy.2014.08.011
http://localhost/t...ganizacniJednotka	22310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 36 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software