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Description
  • The surface of beeswax seals shows a tendency to become covered with a white crystallic layer, composed mainly of unsaturated hydrocarbons. In order to obtain deeper insight into the nature of this adverse phenomenon, the thermal properties of the efflorescence and the pseudobinary mixtures efflorescence/beeswax were studied employing DSC and FTIR methods. The results are in agreement with the hypothesis that a primary cause of the problem is the limited miscibility of both pseudocomponents. Although a certain amount of alkenes can be ?tolerated? in recrystallized beeswax, the resulting mixture is metastable. The possible delayed crystallization of alkenes is then connected with the development of the efflorescence.
  • The surface of beeswax seals shows a tendency to become covered with a white crystallic layer, composed mainly of unsaturated hydrocarbons. In order to obtain deeper insight into the nature of this adverse phenomenon, the thermal properties of the efflorescence and the pseudobinary mixtures efflorescence/beeswax were studied employing DSC and FTIR methods. The results are in agreement with the hypothesis that a primary cause of the problem is the limited miscibility of both pseudocomponents. Although a certain amount of alkenes can be ?tolerated? in recrystallized beeswax, the resulting mixture is metastable. The possible delayed crystallization of alkenes is then connected with the development of the efflorescence. (en)
Title
  • Efflorescence on the surface of beeswax seals: A calorimetric study.
  • Efflorescence on the surface of beeswax seals: A calorimetric study. (en)
skos:prefLabel
  • Efflorescence on the surface of beeswax seals: A calorimetric study.
  • Efflorescence on the surface of beeswax seals: A calorimetric study. (en)
skos:notation
  • RIV/60461373:22310/13:43895452!RIV14-MSM-22310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S
http://linked.open...iv/cisloPeriodika
  • 20 August 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 72098
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/13:43895452
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • unsaturated hydrocarbons; wax-bloom; efflorescence; seals; beeswax (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [E05010DF3E5D]
http://linked.open...i/riv/nazevZdroje
  • Termochimica Acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 566
http://linked.open...iv/tvurceVysledku
  • Bartl, Benjamin
  • Trejbal, Jiří
  • Ďurovič, Michal
  • Havlín, Jakub
http://linked.open...ain/vavai/riv/wos
  • 000322685700042
issn
  • 0022-0248
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tca.2013.06.010
http://localhost/t...ganizacniJednotka
  • 22310
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