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  • Perillyl acetate is a fragrance compd. that was prepd. by the reaction of beta-pinenoxide with acetic anhydride and using acetic acid as an acid catalyst. Several selected catalysts were tested (homogeneous: phosphoric acid, boric acid, acetic acid, and citric acid; heterogeneous: zeolite USY, SSA, and montmorillonite K-10) and the reaction conditions optimized for this reaction. The yield 78.7 % of perillyl acetate was obtained. Mayol (4-isopropylcyclohexylmethanol), a valuable fragrance compd., was further obtained by a two-step synthesis from perillyl acetate. Firstly, perillyl acetate was sapond. to perillyl alc. The yield of alc. was 94.4 %. The last step of the entire prepn. was the hydrogenation of perillyl alc. to Mayol. The yield of the desired product of this reaction was 94.6 %.
  • Perillyl acetate is a fragrance compd. that was prepd. by the reaction of beta-pinenoxide with acetic anhydride and using acetic acid as an acid catalyst. Several selected catalysts were tested (homogeneous: phosphoric acid, boric acid, acetic acid, and citric acid; heterogeneous: zeolite USY, SSA, and montmorillonite K-10) and the reaction conditions optimized for this reaction. The yield 78.7 % of perillyl acetate was obtained. Mayol (4-isopropylcyclohexylmethanol), a valuable fragrance compd., was further obtained by a two-step synthesis from perillyl acetate. Firstly, perillyl acetate was sapond. to perillyl alc. The yield of alc. was 94.4 %. The last step of the entire prepn. was the hydrogenation of perillyl alc. to Mayol. The yield of the desired product of this reaction was 94.6 %. (en)
Title
  • Preparation and utilization of perillyl acetate
  • Preparation and utilization of perillyl acetate (en)
skos:prefLabel
  • Preparation and utilization of perillyl acetate
  • Preparation and utilization of perillyl acetate (en)
skos:notation
  • RIV/60461373:22310/12:43894068!RIV13-GA0-22310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GD203/08/H032), S, Z(MSM6046137301)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 161331
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/12:43894068
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  • heterogeneous catalysts; homogeneous catalysts; beta-pinenoxide; perillyl acetate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [DE2C03369701]
http://linked.open...i/riv/nazevZdroje
  • Res. Chem. Intermed
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 38
http://linked.open...iv/tvurceVysledku
  • Červený, Libor
  • Paterová, Iva
  • Vyskočilová, Eliška
  • Štekrová, Martina
http://linked.open...ain/vavai/riv/wos
  • 000308964900032
http://linked.open...n/vavai/riv/zamer
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  • 0922-6168
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  • 22310
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