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  • Polysaccharides are widely used auxiliaries in ceramic technology today. Typical microstructures are shown for porous alumina made with wheat flour, porous alumina-zirconia composites (ZTA ceramics) made with corn starch and dense zirconia ceramics made with carrageenan. SEM mircographs indicate a hierarchically porous microstructure with very large (approx. 200 microns) pores for alumina made with wheat flour (in fact a foaming-assisted starch consolidation process) and confirm that the mercury porosimetry results must be interpreted in terms of pore throat size distributions (also for ZTA ceramics made with corn starch). Total porosities of 60 % can readily be obtained when using wheat flour (50 % with corn starch). Zirconia ceramics made by carrageenan gelcasting can be sintered to almost full density (total porosities { 2 %) while retaining a reasonably fine grain size (0.5-2 microns). However, dimensional control may be a problem due to the high shrinkage for carrageenan gelcasting (more than 40 %, in contrast to 20-25 % for starch consolidation casting). Reasons for these differences are discussed.
  • Polysaccharides are widely used auxiliaries in ceramic technology today. Typical microstructures are shown for porous alumina made with wheat flour, porous alumina-zirconia composites (ZTA ceramics) made with corn starch and dense zirconia ceramics made with carrageenan. SEM mircographs indicate a hierarchically porous microstructure with very large (approx. 200 microns) pores for alumina made with wheat flour (in fact a foaming-assisted starch consolidation process) and confirm that the mercury porosimetry results must be interpreted in terms of pore throat size distributions (also for ZTA ceramics made with corn starch). Total porosities of 60 % can readily be obtained when using wheat flour (50 % with corn starch). Zirconia ceramics made by carrageenan gelcasting can be sintered to almost full density (total porosities { 2 %) while retaining a reasonably fine grain size (0.5-2 microns). However, dimensional control may be a problem due to the high shrinkage for carrageenan gelcasting (more than 40 %, in contrast to 20-25 % for starch consolidation casting). Reasons for these differences are discussed. (en)
Title
  • Polysaccharides as creators of different ceramic microstructures
  • Polysaccharides as creators of different ceramic microstructures (en)
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  • Polysaccharides as creators of different ceramic microstructures
  • Polysaccharides as creators of different ceramic microstructures (en)
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  • RIV/60461373:22310/11:43892930!RIV12-MSM-22310___
http://linked.open...avai/riv/aktivita
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  • Z(MSM6046137302)
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  • 221284
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  • RIV/60461373:22310/11:43892930
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  • Polysaccharides, starch, wheat flour, carrageenan, dense ceramics, porous ceramics, porosity, pore size, alumina, zirconia, alumina-zirconia composites (ZTA ceramics) (en)
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  • [1B9573CCD8B3]
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  • Praha
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  • Praha
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  • Proceedings of the 7th International Conference on Polysaccharides - Glycoscience
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http://linked.open...UplatneniVysledku
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  • Cílová, Zuzana
  • Gregorová, Eva
  • Pabst, Willi
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http://linked.open...n/vavai/riv/zamer
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  • Česká společnost chemická
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  • 978-80-86238-90-6
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  • 22310
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