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  • Na(+) ions have a detrimental effect on the photocatalytic activity of thin sot gel films deposited on soda lime glass due to their diffusion into the film during the calcination process. Given that the content of sodium in glass substrate might be the crucial parameter in determining the activity of a photocatalyst, the aim of the present work was the comparison of the photoinduced properties of a thin TiO(2) film prepared on three different glass substrates namely on quartz (Q) glass, borosilicate (BS) glass and soda lime (SL) glass which have different sodium content. The prepared layers were characterised by X-ray diffraction and UV-vis spectroscopy. The diffusion of Na(+) from the substrate into the layers was determined by Glow Discharge Atomic Emission Spectroscopy. The photocatalytic activities of the films were assessed using two model pollutant test systems (resazurin/resorufin ink and stearic acid film), which appeared to correlate reasonably well. It was observed that TiO(2) layer on SL glass has a brookite crystalline structure while the TiO(2) layer on BS and Q glass has an anatase crystalline structure. On the other hand, the photodegradation of the model dye on TiO(2) films deposited on Q and BS glass is about an order higher than on SL glass. The low sodium content of BS glass makes it the most suitable substrate for the deposition of photoactive sol gel TiO(2) films. (C) 2011 Elsevier B.V. All rights reserved.
  • Na(+) ions have a detrimental effect on the photocatalytic activity of thin sot gel films deposited on soda lime glass due to their diffusion into the film during the calcination process. Given that the content of sodium in glass substrate might be the crucial parameter in determining the activity of a photocatalyst, the aim of the present work was the comparison of the photoinduced properties of a thin TiO(2) film prepared on three different glass substrates namely on quartz (Q) glass, borosilicate (BS) glass and soda lime (SL) glass which have different sodium content. The prepared layers were characterised by X-ray diffraction and UV-vis spectroscopy. The diffusion of Na(+) from the substrate into the layers was determined by Glow Discharge Atomic Emission Spectroscopy. The photocatalytic activities of the films were assessed using two model pollutant test systems (resazurin/resorufin ink and stearic acid film), which appeared to correlate reasonably well. It was observed that TiO(2) layer on SL glass has a brookite crystalline structure while the TiO(2) layer on BS and Q glass has an anatase crystalline structure. On the other hand, the photodegradation of the model dye on TiO(2) films deposited on Q and BS glass is about an order higher than on SL glass. The low sodium content of BS glass makes it the most suitable substrate for the deposition of photoactive sol gel TiO(2) films. (C) 2011 Elsevier B.V. All rights reserved. (en)
Title
  • Effect of glass substrate and deposition technique on the properties of sol gel TiO(2) thin films
  • Effect of glass substrate and deposition technique on the properties of sol gel TiO(2) thin films (en)
skos:prefLabel
  • Effect of glass substrate and deposition technique on the properties of sol gel TiO(2) thin films
  • Effect of glass substrate and deposition technique on the properties of sol gel TiO(2) thin films (en)
skos:notation
  • RIV/60461373:22310/11:43892460!RIV12-MSM-22310___
http://linked.open...avai/riv/aktivita
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  • P(1M0577), Z(MSM6046137301)
http://linked.open...iv/cisloPeriodika
  • 1
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  • 196284
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/11:43892460
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  • Na(+) ions; Sol gel; TiO(2) thin film; Substrate; Glass (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [E450ED64A24A]
http://linked.open...i/riv/nazevZdroje
  • Journal of Photochemistry and Photobiology A: Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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  • 222
http://linked.open...iv/tvurceVysledku
  • Kment, Štěpán
  • Krýsa, Josef
  • Kšírová, Petra
  • Mills, Andrew
http://linked.open...ain/vavai/riv/wos
  • 000295241600013
http://linked.open...n/vavai/riv/zamer
issn
  • 1010-6030
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jphotochem.2011.05.005
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  • 22310
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