About: Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene

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About: Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	It was observed that 4-methyl-endo-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene, when heated at 100°C, isomerizes to a thermodynamically more stable isomer, 2-methyl-endo-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene, through [3,3]-sigmatropic rearrangement. The kinetics of this thermal rearrangement was studied in the liquid phase in the temperature range of 80 - 140°C and kinetic parameters were evaluated. It was observed that 4-methyl-endo-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene, when heated at 100°C, isomerizes to a thermodynamically more stable isomer, 2-methyl-endo-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene, through [3,3]-sigmatropic rearrangement. The kinetics of this thermal rearrangement was studied in the liquid phase in the temperature range of 80 - 140°C and kinetic parameters were evaluated. (en)
Title	Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene (en)
skos:prefLabel	Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene Rearrangement of 4-methyldicyclopentadiene to 2-methyldicyclopentadiene (en)
skos:notation	RIV/60461373:22310/11:43892034!RIV12-MPO-22310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(FT-TA3/079)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Krupka, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	225873
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/11:43892034
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	kinetics, methyldicyclopentadiene, Cope rearrangement, activation energy (en)
http://linked.open.../riv/klicoveSlovo	activation energy kinetics Cope rearrangement methyldicyclopentadiene
http://linked.open...odStatuVydavatele	SK - Slovenská republika
http://linked.open...ontrolniKodProRIV	[02AC9ED52800]
http://linked.open...i/riv/nazevZdroje	Petroleum and Coal
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...vavai/riv/projekt	*Research of the progressive chemical products based on dicyclopentadiene.
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	53
http://linked.open...iv/tvurceVysledku	Krupka, Jiří
issn	1337-7027
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	22310

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