About: Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production

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About: Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Abstract Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantio?selectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes. Preferential hydrogenation of one functional group in a molecule over another is the chemoselective process, while regioselective hydrogenation is the prefe-rential formation of one constitutional isomer of the product in a reaction in which other isomers may also be formed, and the stereoselective hydrogenation is the formation of an excess of Abstract Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantio?selectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes. Preferential hydrogenation of one functional group in a molecule over another is the chemoselective process, while regioselective hydrogenation is the prefe-rential formation of one constitutional isomer of the product in a reaction in which other isomers may also be formed, and the stereoselective hydrogenation is the formation of an excess of (en)
Title	Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production (en)
skos:prefLabel	Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production (en)
skos:notation	RIV/60461373:22310/10:00023040!RIV11-MSM-22310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6046137301)
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Klusoň, Petr Floriš, Tomáš
http://linked.open.../riv/druhVysledku	C - Kapitola v knize
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	250585
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/10:00023040
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Chemoselective Hydrogenation; Enantioselective Hydrogenation; Immobilized Complexes (en)
http://linked.open.../riv/klicoveSlovo	Chemoselective Hydrogenation Enantioselective Hydrogenation Immobilized Complexes
http://linked.open...ontrolniKodProRIV	[E9E66040B4C1]
http://linked.open...i/riv/mistoVydani	Berlin
http://linked.open...i/riv/nazevZdroje	Catalysis by Metal Complexes
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...v/pocetStranKnihy	458 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2010
http://linked.open...iv/tvurceVysledku	Floriš, Tomáš Klusoň, Petr Notheisz, Ferenz Zsigmond, Agnes
http://linked.open...n/vavai/riv/zamer	Catalytic processes in chemistry and chemical technology
number of pages	77 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Springer-Verlag
https://schema.org/isbn	978-90-481-3695-7
http://localhost/t...ganizacniJednotka	22310

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