About: Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Hydrogenation of phenylacetylene (PA) and 3-phenylpropyne (PP) was carried out using [Rh(diene)Cl](2) complexes (diene is hexadiene (HD), cycloocta-1,5-diene (COD), norborna-2,5-diene (NBD)) in their immobilized forms and compared with hydrogenation in homogeneous arrangement. Immobilization brings significant increase of the catalytic activity and product selectivity in the step-wise hydrogenation to corresponding vinyl-resp. allyl-benzenes. Diene-ligand effect was apparent in PA hydrogenation: the product selectivity decreased in order Rh(HD) > Rh(NBD) > Rh(COD) and catalytic activity decreased in order Rh(HD) > Rh(COD) > Rh(NBD). Hydrogenation of phenylacetylene (PA) and 3-phenylpropyne (PP) was carried out using [Rh(diene)Cl](2) complexes (diene is hexadiene (HD), cycloocta-1,5-diene (COD), norborna-2,5-diene (NBD)) in their immobilized forms and compared with hydrogenation in homogeneous arrangement. Immobilization brings significant increase of the catalytic activity and product selectivity in the step-wise hydrogenation to corresponding vinyl-resp. allyl-benzenes. Diene-ligand effect was apparent in PA hydrogenation: the product selectivity decreased in order Rh(HD) > Rh(NBD) > Rh(COD) and catalytic activity decreased in order Rh(HD) > Rh(COD) > Rh(NBD). (en)
Title	Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions (en)
skos:prefLabel	Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions Hydrogenation of phenylacetylene and 3-phenylpropyne using Rh(diene) complexes under homogeneous and heterogeneous conditions (en)
skos:notation	RIV/60461373:22310/10:00022981!RIV11-GA0-22310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/07/1239), P(GA104/09/1435), P(GD203/08/H032), Z(MSM0021620857), Z(MSM6046137301)
http://linked.open...iv/cisloPeriodika	372
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Kačer, Petr Červený, Libor Vyskočilová, Eliška
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	262481
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/10:00022981
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	phenylacetylene; Rh(dienic)complex; selective hydrogenation (en)
http://linked.open.../riv/klicoveSlovo	Rh(dienic)complex selective hydrogenation phenylacetylene
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[0EAA0BD94E2A]
http://linked.open...i/riv/nazevZdroje	Applied Catalysis
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Advanced catalytic processes for preparation of organic photoelectronic materials Advanced catalytic processes and materials Modern aspects of partial hydrogenation of CC triple bond
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	2010
http://linked.open...iv/tvurceVysledku	Kačer, Petr Sedláček, Jan Svoboda, Jan Vohlídal, Jiří Červený, Libor Leitmannová-Vyskočilová, Eliška
http://linked.open...ain/vavai/riv/wos	000273933800005
http://linked.open...n/vavai/riv/zamer	Catalytic processes in chemistry and chemical technology Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0926-860X
number of pages	5 (xsd:int)
http://localhost/t...ganizacniJednotka	22310

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