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  • The properties of nanocrystalline ceramics are in many respects unique because the grain boundaries, which are in reality discontinuities of small but finite thickness, attain significant volume fractions when the average grain size is below approx. 100 nm. The simplest way to model the grain size dependence of properties consists in considering the nanocrystalline material as a two-phase composite, i.e. as a binary mixture of two separate phases, a crystalline core phase (with properties corresponding to the bulk solid) and a disordered, glass-like grain boundary phase. When this viewpoint is adopted, the laws of composite theory (micromechanics) can be applied to estimate the effective properties. In this chapter this is done for single-phase ceramic systems with monodisperse grain size by invoking a unit-cell approach using cubic, tetrakaidecahedral and anisometric grain shapes (trigonal, tetragonal and hexagonal prisms, oblate and prolate). In particular, the effective Young?s modulus and thermal
  • The properties of nanocrystalline ceramics are in many respects unique because the grain boundaries, which are in reality discontinuities of small but finite thickness, attain significant volume fractions when the average grain size is below approx. 100 nm. The simplest way to model the grain size dependence of properties consists in considering the nanocrystalline material as a two-phase composite, i.e. as a binary mixture of two separate phases, a crystalline core phase (with properties corresponding to the bulk solid) and a disordered, glass-like grain boundary phase. When this viewpoint is adopted, the laws of composite theory (micromechanics) can be applied to estimate the effective properties. In this chapter this is done for single-phase ceramic systems with monodisperse grain size by invoking a unit-cell approach using cubic, tetrakaidecahedral and anisometric grain shapes (trigonal, tetragonal and hexagonal prisms, oblate and prolate). In particular, the effective Young?s modulus and thermal (en)
Title
  • Phase mixture models and unit-cell calculations for the effective elastic and thermal properties of nanocrystalline ceramics
  • Phase mixture models and unit-cell calculations for the effective elastic and thermal properties of nanocrystalline ceramics (en)
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  • Phase mixture models and unit-cell calculations for the effective elastic and thermal properties of nanocrystalline ceramics
  • Phase mixture models and unit-cell calculations for the effective elastic and thermal properties of nanocrystalline ceramics (en)
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  • RIV/60461373:22310/10:00022973!RIV11-MSM-22310___
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  • P(IAA401250703), Z(MSM6046137302)
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  • 278728
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  • RIV/60461373:22310/10:00022973
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  • Phase mixture models; unit cells; nanocrystalline ceramics; alumina; zirconia; Young's modulus; thermal conductivity. (en)
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  • [78A9EFA840F8]
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  • New York
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  • neuveden
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  • Advances in Nanotechnology, Volume 3
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  • Gregorová, Eva
  • Pabst, Willi
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number of pages
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  • Nova Science Publishers,Hauppauge
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  • 978-1-61668-161-6
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  • 22310
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