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rdf:type
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Description
| - Cu-mediated arylation of 7-methyl-10-oxo-9,10-dihydropyrimido[1,2-a]purine (1) in dichloromethane or N2-dimethylaminomethyleneguanine (2) in methanol at the presence of TMEDA as a base/ligand leads to the preferential formation of 1-aryl-7-methyl-10-oxo-9,10-dihydropyrimido[1,2-a]purines (4) and 7-aryl-N2-dimethylaminomethyleneguanines (7), respectively. These compounds can be easily hydrolyzed to the corresponding 7- arylguanines. Similarly arylation of N6-dimethylaminomethyleneadenine (15) at the presence of o-phenanthroline instead of TMEDA affords mainly 7-aryladenines after hydrolysis.
- Cu-mediated arylation of 7-methyl-10-oxo-9,10-dihydropyrimido[1,2-a]purine (1) in dichloromethane or N2-dimethylaminomethyleneguanine (2) in methanol at the presence of TMEDA as a base/ligand leads to the preferential formation of 1-aryl-7-methyl-10-oxo-9,10-dihydropyrimido[1,2-a]purines (4) and 7-aryl-N2-dimethylaminomethyleneguanines (7), respectively. These compounds can be easily hydrolyzed to the corresponding 7- arylguanines. Similarly arylation of N6-dimethylaminomethyleneadenine (15) at the presence of o-phenanthroline instead of TMEDA affords mainly 7-aryladenines after hydrolysis. (en)
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Title
| - New Approach to the Synthesis of N7-Arylguanines and N7-Aryladenines
- New Approach to the Synthesis of N7-Arylguanines and N7-Aryladenines (en)
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skos:prefLabel
| - New Approach to the Synthesis of N7-Arylguanines and N7-Aryladenines
- New Approach to the Synthesis of N7-Arylguanines and N7-Aryladenines (en)
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skos:notation
| - RIV/60461373:22310/09:00021595!RIV10-MSM-22310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/06/0888), Z(MSM6046137301)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22310/09:00021595
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Nucleobases; Nitrogen heterocycles; Copper; Boron (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - European Journal of Organic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...iv/tvurceVysledku
| - Dvořáková, Hana
- Dvořák, Dalimil
- Keder, Roman
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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