About: Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media.

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About: Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media. Goto Sponge NotDistinct Permalink

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Description	Electrosynthesis of poly(2-methyl-thieno[3,2-b]benzothiophene) [poly(2-MeTBT)] and poly(3-methyl-thieno[3,2-b]benzothiophene) [poly(3-MeTBT)], was performed by anodic oxidation of 2-MeTBT and 3-MeTBT on Pt electrode in 0.1M LiClO4 acetonitrile solution and in a partially aqueous micellar medium (water/methanol, 9/91, v/v) containing 0.39M perchloric acid and 0.1MSDS (sodium dodecylsulfate). The electrochemical characteristics and FT-IR spectra of 2-MeTBT and 3-MeTBT, as well as their optical properties were studied. The corresponding polymers were investigated by cyclic voltammetry, MALDI-TOF, FT-IR, electronic absorption and fluorescence spectroscopy. A theoretical approach based on molecular orbital (MO) calculations and using a radical-cation electropolymerisation mechanism, was proposed for the oligomer structural characterization. Electrosynthesis of poly(2-methyl-thieno[3,2-b]benzothiophene) [poly(2-MeTBT)] and poly(3-methyl-thieno[3,2-b]benzothiophene) [poly(3-MeTBT)], was performed by anodic oxidation of 2-MeTBT and 3-MeTBT on Pt electrode in 0.1M LiClO4 acetonitrile solution and in a partially aqueous micellar medium (water/methanol, 9/91, v/v) containing 0.39M perchloric acid and 0.1MSDS (sodium dodecylsulfate). The electrochemical characteristics and FT-IR spectra of 2-MeTBT and 3-MeTBT, as well as their optical properties were studied. The corresponding polymers were investigated by cyclic voltammetry, MALDI-TOF, FT-IR, electronic absorption and fluorescence spectroscopy. A theoretical approach based on molecular orbital (MO) calculations and using a radical-cation electropolymerisation mechanism, was proposed for the oligomer structural characterization. (en) Byla studována syntéza, elektropolymerace, optické vlastnosti série nových polymerů odvozených od methylthienobenzothiofenů. (cs)
Title	Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media. Eelektrochemické, spektrální a teoretické studium nových methylthienobenzothiofenů a jejich polymerů (cs) Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media. (en)
skos:prefLabel	Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media. Eelektrochemické, spektrální a teoretické studium nových methylthienobenzothiofenů a jejich polymerů (cs) Electrochemical, spectral and theoretical studies of two new methylthieno[3,2-b]benzothiophenes and their polymers electrosynthesized in organic and micellar media. (en)
skos:notation	RIV/60461373:22310/08:00020375!RIV09-MSM-22310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC 176), Z(MSM 223100001)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Svoboda, Jiří Kozmík, Václav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	365788
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/08:00020375
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electropoyĺymerization; methylthienobenzothiophenes; structura; conductivity (en)
http://linked.open.../riv/klicoveSlovo	conductivity electropoyĺymerization methylthienobenzothiophenes structura
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[17F5511C5DEA]
http://linked.open...i/riv/nazevZdroje	Synthetic Metals
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20176
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	158
http://linked.open...iv/tvurceVysledku	Svoboda, Jiří Adenier, Alain Kozmík, Václav Aaron, Jean-Jacques Lo, Ch. Maurel, Francois
http://linked.open...ain/vavai/riv/wos	000255107800002
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223100001
issn	0379-6779
number of pages	19 (xsd:int)
http://localhost/t...ganizacniJednotka	22310

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