About: Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure.     Goto   Sponge   NotDistinct   Permalink

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  • The electropolymerization or thieno[3,2-b]indole (TI), 6-methoxythieno[3,2-b]indole (MeOTI) and N-methylthieno[3,2-b]indole (N-MeTI) was performed in organic solvents with the aim to prepare new conducting materials. TI and MeOTI anodic oxidation led to the rormation on platinum electrodes or electroactive polymer films that were characterized by cyclic voltammetry, quartz microbalance, MALDI-TOF, FT-IR spectroscopy and scanning electron microscopy. MALDI-TOF mas s spectrometry indicates that films are mainly constituted or short-chain oligomers. FT-IR studies and molecular orbital calculations show that polymers present coupling occurring on the thiophene and phenyl rings. The great differences observed between the electrochel11ical and physicochemical properties or the various polymer films were mainly induced by the location and electron-donating effects or substituents in the different monomers. Substitution influenced not only electroactivity, chain length and film morphology, but also the electr
  • The electropolymerization or thieno[3,2-b]indole (TI), 6-methoxythieno[3,2-b]indole (MeOTI) and N-methylthieno[3,2-b]indole (N-MeTI) was performed in organic solvents with the aim to prepare new conducting materials. TI and MeOTI anodic oxidation led to the rormation on platinum electrodes or electroactive polymer films that were characterized by cyclic voltammetry, quartz microbalance, MALDI-TOF, FT-IR spectroscopy and scanning electron microscopy. MALDI-TOF mas s spectrometry indicates that films are mainly constituted or short-chain oligomers. FT-IR studies and molecular orbital calculations show that polymers present coupling occurring on the thiophene and phenyl rings. The great differences observed between the electrochel11ical and physicochemical properties or the various polymer films were mainly induced by the location and electron-donating effects or substituents in the different monomers. Substitution influenced not only electroactivity, chain length and film morphology, but also the electr (en)
  • The electropolymerization or thieno[3,2-b]indole (TI), 6-methoxythieno[3,2-b]indole (MeOTI) and N-methylthieno[3,2-b]indole (N-MeTI) was performed in organic solvents with the aim to prepare new conducting materials. TI and MeOTI anodic oxidation led to the rormation on platinum electrodes or electroactive polymer films that were characterized by cyclic voltammetry, quartz microbalance, MALDI-TOF, FT-IR spectroscopy and scanning electron microscopy. MALDI-TOF mas s spectrometry indicates that films are mainly constituted or short-chain oligomers. FT-IR studies and molecular orbital calculations show that polymers present coupling occurring on the thiophene and phenyl rings. The great differences observed between the electrochel11ical and physicochemical properties or the various polymer films were mainly induced by the location and electron-donating effects or substituents in the different monomers. Substitution influenced not only electroactivity, chain length and film morphology, but also the electr (cs)
Title
  • Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure.
  • Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure. (en)
  • Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure. (cs)
skos:prefLabel
  • Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure.
  • Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure. (en)
  • Novel conducting polymers based on thieno[3,2-b]indoles: Electrochemical properties and molecular structure. (cs)
skos:notation
  • RIV/60461373:22310/05:00013771!RIV06-MSM-22310___
http://linked.open.../vavai/riv/strany
  • 93-103
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 223100001)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 533331
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22310/05:00013771
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • thienoindoles (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [1393E38F4D3D]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 581
http://linked.open...iv/tvurceVysledku
  • Svoboda, Jiří
  • Adenier, Alain
  • Mézlová, Marie
  • Aaron, Jean-Jacques
  • Maurel, Francois
  • Chane-Ching, Kathleen
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-0728
number of pages
http://localhost/t...ganizacniJednotka
  • 22310
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