Attributes | Values |
---|
rdf:type
| |
Description
| - 1,5-Diaryl-3,3-diphenylpentane-1,5-diones 3a-d react with Al2Se3-HCl-AcOH reagent to give the 2,6-diaryl-4,4-diphenyl-4H-selenopyrans 4a-d in satisfactory yields while the same procedure starting from 1,5-diketone 5 affords small amounts of spiroheterocycle 6. 2,4,4,6-Tetraphenyl-4H-selenopyran 4a can be brominated or nitrated at positions 3 and 5 to give substituted derivatives 7-9. Dibromo derivatives 4c and 7 were converted with copper(I) cyanide to dicyano derivatives 4e and 10,11, respectively. Similarly to 4H-pyrans 1 and 4H-thiopyrans 2, the 1-selena analogues 4a-d and 8 exhibit solid state photocolouration which was investigated in terms of dispersive first-order reaction kinetics. The influence of selenium heteroatom on the
- 1,5-Diaryl-3,3-diphenylpentane-1,5-diones 3a-d react with Al2Se3-HCl-AcOH reagent to give the 2,6-diaryl-4,4-diphenyl-4H-selenopyrans 4a-d in satisfactory yields while the same procedure starting from 1,5-diketone 5 affords small amounts of spiroheterocycle 6. 2,4,4,6-Tetraphenyl-4H-selenopyran 4a can be brominated or nitrated at positions 3 and 5 to give substituted derivatives 7-9. Dibromo derivatives 4c and 7 were converted with copper(I) cyanide to dicyano derivatives 4e and 10,11, respectively. Similarly to 4H-pyrans 1 and 4H-thiopyrans 2, the 1-selena analogues 4a-d and 8 exhibit solid state photocolouration which was investigated in terms of dispersive first-order reaction kinetics. The influence of selenium heteroatom on the (en)
|
Title
| - Substituted 2,4,4,6-tetraphenyl-4H-selenopyrans: preparation, photocolouration and 4H-selenopyran ring geometry; an X-ray and DFT calculation study
- Substituted 2,4,4,6-tetraphenyl-4H-selenopyrans: preparation, photocolouration and 4H-selenopyran ring geometry; an X-ray and DFT calculation study (en)
|
skos:prefLabel
| - Substituted 2,4,4,6-tetraphenyl-4H-selenopyrans: preparation, photocolouration and 4H-selenopyran ring geometry; an X-ray and DFT calculation study
- Substituted 2,4,4,6-tetraphenyl-4H-selenopyrans: preparation, photocolouration and 4H-selenopyran ring geometry; an X-ray and DFT calculation study (en)
|
skos:notation
| - RIV/60461373:22310/02:00006483!RIV/2004/MSM/223104/N
|
http://linked.open.../vavai/riv/strany
| |
http://linked.open...avai/riv/aktivita
| |
http://linked.open...avai/riv/aktivity
| |
http://linked.open...iv/cisloPeriodika
| |
http://linked.open...vai/riv/dodaniDat
| |
http://linked.open...aciTvurceVysledku
| |
http://linked.open.../riv/druhVysledku
| |
http://linked.open...iv/duvernostUdaju
| |
http://linked.open...titaPredkladatele
| |
http://linked.open...dnocenehoVysledku
| |
http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22310/02:00006483
|
http://linked.open...riv/jazykVysledku
| |
http://linked.open.../riv/klicovaSlova
| - 2,4,4,6-tetraphenyl-4H-selenopyrans (en)
|
http://linked.open.../riv/klicoveSlovo
| |
http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
|
http://linked.open...ontrolniKodProRIV
| |
http://linked.open...i/riv/nazevZdroje
| - Journal Chemical Society, Perkin Transactions 2
|
http://linked.open...in/vavai/riv/obor
| |
http://linked.open...ichTvurcuVysledku
| |
http://linked.open...cetTvurcuVysledku
| |
http://linked.open...ocetUcastnikuAkce
| |
http://linked.open...nichUcastnikuAkce
| |
http://linked.open...UplatneniVysledku
| |
http://linked.open...v/svazekPeriodika
| |
http://linked.open...iv/tvurceVysledku
| - Böhm, Stanislav
- Nešpůrek, Stanislav
- Čejka, Jan
- Šebek, Pavel
- Kroulík, Jiří
- Koshets, Igor
|
http://linked.open...n/vavai/riv/zamer
| |
issn
| |
number of pages
| |
http://localhost/t...ganizacniJednotka
| |