About: Novel rearrngement of secondary alkoxyalkyl radicals during addition to dooble bond. Steric shielding in the formation of tertiary alkoxyethyl radicals

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About: Novel rearrngement of secondary alkoxyalkyl radicals during addition to dooble bond. Steric shielding in the formation of tertiary alkoxyethyl radicals Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The participation of a 1,3-hydrogen shift in initially formed secondary alkoxyethyl radicals R1R2CH-O-CHÖ-CH3 during their free-radical chain addns. to Me 2,3,3-trifluoroacrylate has been confirmed using a deuterium marked additive. Indirect evidence has been obtained for a partial 1,3-hydrogen shift in secondary radicals CH3(CH2)n-CHÖ-O-CH3 to primary radicals CH3(CH2)n-CH2-O-CH2Ö. Initial formation of tertiary alkoxyethyl radicals R1R2CÖ-O-CHR3R4 in the propagation step was not obsd. due to steric factors. The participation of a 1,3-hydrogen shift in initially formed secondary alkoxyethyl radicals R1R2CH-O-CHÖ-CH3 during their free-radical chain addns. to Me 2,3,3-trifluoroacrylate has been confirmed using a deuterium marked additive. Indirect evidence has been obtained for a partial 1,3-hydrogen shift in secondary radicals CH3(CH2)n-CHÖ-O-CH3 to primary radicals CH3(CH2)n-CH2-O-CH2Ö. Initial formation of tertiary alkoxyethyl radicals R1R2CÖ-O-CHR3R4 in the propagation step was not obsd. due to steric factors. (en)
Title	Novel rearrngement of secondary alkoxyalkyl radicals during addition to dooble bond. Steric shielding in the formation of tertiary alkoxyethyl radicals Novel rearrngement of secondary alkoxyalkyl radicals during addition to dooble bond. Steric shielding in the formation of tertiary alkoxyethyl radicals (en)
skos:prefLabel	Novel rearrngement of secondary alkoxyalkyl radicals during addition to dooble bond. Steric shielding in the formation of tertiary alkoxyethyl radicals Novel rearrngement of secondary alkoxyalkyl radicals during addition to dooble bond. Steric shielding in the formation of tertiary alkoxyethyl radicals (en)
skos:notation	RIV/60461373:22310/02:00006389!RIV/2004/MSM/223104/N
http://linked.open.../vavai/riv/strany	481-485
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 223100001)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Böhm, Stanislav Hajduch, Jan Paleta, Oldřich
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	656061
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/02:00006389
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	alkoxyalkyl radicals; radical rearrangement; radical addition (en)
http://linked.open.../riv/klicoveSlovo	radical addition alkoxyalkyl radicals radical rearrangement
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[D9DB5FA9BAD5]
http://linked.open...i/riv/nazevZdroje	Tetrahedron Letters
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	43
http://linked.open...iv/tvurceVysledku	Böhm, Stanislav Hajduch, Jan Paleta, Oldřich
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223100001
issn	0040-4039
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	22310

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