About: Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury

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About: Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Electroreductions of Ni2+, Cu2+ and Zn2+ complexes of azinyl (pyridin-2-yl, pyridazin-3-yl, pyrimidin-2-yl, pyrimidin-4-yl, pyrazinyl) methyl ketoximes on mercury electrode were studied using dc polarography. Three different types of complex behaviour onthe mercury electrode were observed: In the Ni2+ complexes, the hydroxyimino group of the ligand is reduced, whereas in the Cu2+ complexes, the reduction proceeds on the metal ion. With Zn2+complex of methyl pyridin-2-yl ketoxime, only reduction waves o f the uncoordinated ligand and metal were observed due to a rapid decomplexation pre-equilibrium. Electroreductions of Ni2+, Cu2+ and Zn2+ complexes of azinyl (pyridin-2-yl, pyridazin-3-yl, pyrimidin-2-yl, pyrimidin-4-yl, pyrazinyl) methyl ketoximes on mercury electrode were studied using dc polarography. Three different types of complex behaviour onthe mercury electrode were observed: In the Ni2+ complexes, the hydroxyimino group of the ligand is reduced, whereas in the Cu2+ complexes, the reduction proceeds on the metal ion. With Zn2+complex of methyl pyridin-2-yl ketoxime, only reduction waves o f the uncoordinated ligand and metal were observed due to a rapid decomplexation pre-equilibrium. (en)
Title	Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury (en)
skos:prefLabel	Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury (en)
skos:notation	RIV/60461373:22310/01:00003979!RIV/2004/MSM/223104/N
http://linked.open.../vavai/riv/strany	170-184
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/97/0805), P(GA203/99/M037), Z(AV0Z4040901), Z(AV0Z5052915), Z(MSM 113100001), Z(MSM 223100001)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Liška, František Cibulka, Radek
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemické technologie
http://linked.open...dnocenehoVysledku	679106
http://linked.open...ai/riv/idVysledku	RIV/60461373:22310/01:00003979
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Complexes, Electrochemistry, Oximes, Polarography, Reductions, Crystal structure determination (en)
http://linked.open.../riv/klicoveSlovo	Electrochemistry Crystal structure determination Reductions Oximes Complexes Polarography
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[6DBEAFD17967]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Electrochemical and NMR investigation of the hydrolytic metalloenzyme models Centre of molecular and crystal structures
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	66
http://linked.open...iv/tvurceVysledku	Cibulka, Radek Císařová, Ivana Ludvík, Jiří Ondráček, Jan Liška, František
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20113100001 Regulace a signální cesty uplatňující se v genové expresi, imunitě, onkogenezi, replikaci virů, tvorbě buněčných struktur, chování buněk, vývoji a oplození http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223100001
issn	0010-0765
number of pages	15 (xsd:int)
http://localhost/t...ganizacniJednotka	22310

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