About: Experimental and theoretical study on the complexation of Ca2+ with beauvericin

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Ca2+(aq) + 1 center dot Sr2+(nb) a double dagger%22 1 center dot Ca2+(nb) + Sr2+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K (ex)(Ca2+, 1 center dot Sr2+) = 1.1 +/- A 0.1. Further, the stability constant of the 1 center dot Ca2+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 A degrees C: log beta (nb)(1 center dot Ca2+) = 10.1 +/- A 0.2. Finally, by using quantum mechanical density functional level of theory calculations, the most probable structures of the non-hydrated 1 center dot Ca2+ and hydrated 1 center dot Ca2+center dot H2O complex species were predicted. From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Ca2+(aq) + 1 center dot Sr2+(nb) a double dagger%22 1 center dot Ca2+(nb) + Sr2+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K (ex)(Ca2+, 1 center dot Sr2+) = 1.1 +/- A 0.1. Further, the stability constant of the 1 center dot Ca2+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 A degrees C: log beta (nb)(1 center dot Ca2+) = 10.1 +/- A 0.2. Finally, by using quantum mechanical density functional level of theory calculations, the most probable structures of the non-hydrated 1 center dot Ca2+ and hydrated 1 center dot Ca2+center dot H2O complex species were predicted. (en)
Title	Experimental and theoretical study on the complexation of Ca2+ with beauvericin Experimental and theoretical study on the complexation of Ca2+ with beauvericin (en)
skos:prefLabel	Experimental and theoretical study on the complexation of Ca2+ with beauvericin Experimental and theoretical study on the complexation of Ca2+ with beauvericin (en)
skos:notation	RIV/60460709:41330/13:63627!RIV14-MSM-41330___
http://linked.open...avai/riv/aktivita	S
http://linked.open...avai/riv/aktivity	S
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Makrlík, Emanuel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Česká zemědělská univerzita v Praze / Fakulta životního prostředí
http://linked.open...dnocenehoVysledku	74014
http://linked.open...ai/riv/idVysledku	RIV/60460709:41330/13:63627
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Calcium, Beauvericin, Complexation, Water–nitrobenzene system, Extraction and stability constants, DFT calculations, Structures. (en)
http://linked.open.../riv/klicoveSlovo	Calcium Beauvericin Structures. Water–nitrobenzene system Complexation DFT calculations Extraction and stability constants
http://linked.open...odStatuVydavatele	HU - Maďarsko
http://linked.open...ontrolniKodProRIV	[34961EE59BD8]
http://linked.open...i/riv/nazevZdroje	Journal of Radioanalytical and Nuclear Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	298
http://linked.open...iv/tvurceVysledku	Makrlík, Emanuel Toman, Petr Vaňura, Petr
http://linked.open...ain/vavai/riv/wos	000324546100025
issn	0236-5731
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	41330

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