About: Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using a Synergistic Mixture of Hydrogen Dicarbollylcobaltate and Bis(Diphenylphosphino)Methane Dioxide

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About: Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using a Synergistic Mixture of Hydrogen Dicarbollylcobaltate and Bis(Diphenylphosphino)Methane Dioxide Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+ B-) in the presence of bis(diphenylphosphino) methane dioxide (DPPMDO, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2+, ML22+, ML32+ and ML42+ (M2+ = Ca2+, Sr2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL22+, CaL32+ and CaL42+, where L is DPPMDO, are somewhat higher than those of the corresponding complex species SrL22+, SrL32+ and SrL42+ with the same ligand L. Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+ B-) in the presence of bis(diphenylphosphino) methane dioxide (DPPMDO, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2+, ML22+, ML32+ and ML42+ (M2+ = Ca2+, Sr2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL22+, CaL32+ and CaL42+, where L is DPPMDO, are somewhat higher than those of the corresponding complex species SrL22+, SrL32+ and SrL42+ with the same ligand L. (en)
Title	Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using a Synergistic Mixture of Hydrogen Dicarbollylcobaltate and Bis(Diphenylphosphino)Methane Dioxide Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using a Synergistic Mixture of Hydrogen Dicarbollylcobaltate and Bis(Diphenylphosphino)Methane Dioxide (en)
skos:prefLabel	Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using a Synergistic Mixture of Hydrogen Dicarbollylcobaltate and Bis(Diphenylphosphino)Methane Dioxide Solvent Extraction of Calcium and Strontium into Nitrobenzene by Using a Synergistic Mixture of Hydrogen Dicarbollylcobaltate and Bis(Diphenylphosphino)Methane Dioxide (en)
skos:notation	RIV/60460709:41330/13:60898!RIV14-MSM-41330___
http://linked.open...avai/riv/aktivita	N S
http://linked.open...avai/riv/aktivity	N, S
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Makrlík, Emanuel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Česká zemědělská univerzita v Praze / Fakulta životního prostředí
http://linked.open...dnocenehoVysledku	106279
http://linked.open...ai/riv/idVysledku	RIV/60460709:41330/13:60898
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Calcium, strontium, bis(diphenylphosphino)methane dioxide, hydrogen dicarbollylcobaltate, complexation, extraction and stability constants, water-nitrobenzene system (en)
http://linked.open.../riv/klicoveSlovo	strontium Calcium extraction and stability constants hydrogen dicarbollylcobaltate water-nitrobenzene system bis(diphenylphosphino)methane dioxide complexation
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[9745B13CC208]
http://linked.open...i/riv/nazevZdroje	ACTA CHIMICA SLOVENICA
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	60
http://linked.open...iv/tvurceVysledku	Makrlík, Emanuel Vaňura, Petr Spíchal, Zdeněk Selucký, P.
http://linked.open...ain/vavai/riv/wos	000317014600030
issn	1318-0207
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	41330

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