About: Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles     Goto   Sponge   NotDistinct   Permalink

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  • The reactions of p-nitrophenyl acetate (PNPA) and p-nitrophenyl benzoate (PNPB) with _-nucleophile oximates i.e., 2, 3-butane dione monoximate, pralidoximate;and other oximates has been studied in the presence of different cationic surfactants. The first order rate constant increases with increasing surfactant concentration. The extent of acceleration is dependent of head group of surfactants. The reaction of PNPA with oximes gains greater rate enhancements than the corresponding reaction of PNPB in the presence of cationic surfactants.
  • The reactions of p-nitrophenyl acetate (PNPA) and p-nitrophenyl benzoate (PNPB) with _-nucleophile oximates i.e., 2, 3-butane dione monoximate, pralidoximate;and other oximates has been studied in the presence of different cationic surfactants. The first order rate constant increases with increasing surfactant concentration. The extent of acceleration is dependent of head group of surfactants. The reaction of PNPA with oximes gains greater rate enhancements than the corresponding reaction of PNPB in the presence of cationic surfactants. (en)
Title
  • Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles
  • Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles (en)
skos:prefLabel
  • Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles
  • Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles (en)
skos:notation
  • RIV/60162694:G44__/09:00002168!RIV10-MO0-G44_____
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(OPUOFVZ200603)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 321746
http://linked.open...ai/riv/idVysledku
  • RIV/60162694:G44__/09:00002168
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  • oxime; PNPA; PNPB; cetyltributylphosphonium bromide; cationic surfactants (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [49BEF36905D0]
http://linked.open...i/riv/nazevZdroje
  • International Journal of Chemical Kinetics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...v/svazekPeriodika
  • 41
http://linked.open...iv/tvurceVysledku
  • Kuča, Kamil
  • Marek, Jan
  • Ghosh, Kallol K
  • Tiwari, Shuch
  • Kolay, Sancheeta
http://linked.open...ain/vavai/riv/wos
  • 000261706200006
issn
  • 0538-8066
number of pages
http://localhost/t...ganizacniJednotka
  • G44
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