About: The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface

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About: The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	From the extraction measurements, the equilibrium distribution constant Kd(L) for the electroneutral ligand 1,10-phenanthroline between the 1,2-dichlorethane and aqueos phases has been determined in the form log Kd(L)=1,95, where L represents the ligand.Using known thermodynamic parameters and general relations, stability constants of the metal chelate complexes [Ni(phen)]2+, [Ni(phen)2]2+ a [Ni(phen)3]2+ (phen=1,10-phenantroline) in 1,2-dichlorethane saturated with water have been evaluated. It has been found that the stability constants determined in this medium are essentially higher than the corresponding stability constants of these complexes in water. From the extraction measurements, the equilibrium distribution constant Kd(L) for the electroneutral ligand 1,10-phenanthroline between the 1,2-dichlorethane and aqueos phases has been determined in the form log Kd(L)=1,95, where L represents the ligand.Using known thermodynamic parameters and general relations, stability constants of the metal chelate complexes [Ni(phen)]2+, [Ni(phen)2]2+ a [Ni(phen)3]2+ (phen=1,10-phenantroline) in 1,2-dichlorethane saturated with water have been evaluated. It has been found that the stability constants determined in this medium are essentially higher than the corresponding stability constants of these complexes in water. (en)
Title	The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface (en)
skos:prefLabel	The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface The transfer of Ni II- 1,10-phenanthroline complexes across the water / 1,2-dichlorethane interface (en)
skos:notation	RIV/60162694:G14__/99:02000013!RIV/2001/MO0/G14001/N
http://linked.open.../vavai/riv/strany	339
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MO0990100X002)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2001
http://linked.open...aciTvurceVysledku	Božek, František
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ministerstvo obrany / Vysoká vojenská škola pozemního vojska Vyškov
http://linked.open...dnocenehoVysledku	756475
http://linked.open...ai/riv/idVysledku	RIV/60162694:G14__/99:02000013
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Complex; Equilibrium Distribution Constant; Stability Constant; Extraction; Interface; Nickel; 1,10- (en)
http://linked.open.../riv/klicoveSlovo	Interface Complex 1 Extraction 10- Equilibrium Distribution Constant Nickel Stability Constant
http://linked.open...odStatuVydavatele	IE - Irsko
http://linked.open...ontrolniKodProRIV	[9FFE17AAFBF6]
http://linked.open...i/riv/nazevZdroje	Models in Chemistry
http://linked.open...in/vavai/riv/obor	KA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...UplatneniVysledku	1999
http://linked.open...v/svazekPeriodika	136
http://linked.open...iv/tvurceVysledku	Božek, František Makrlik, Emanuel
http://linked.open...n/vavai/riv/zamer	Economic support of state defence with transitive economy.
issn	1217-8969
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	G14

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