About: Cyclosporins of symmetry P2(1) - a series of clathrates

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A series of isomorphous clathrates (cyclosporin A: solvent = 1 : 1) is reported. The structure of the tetrahydrofuran ( 1) and dibutylether (2) clathrates have been determined by X-ray single crystal diffraction. The cyclosporin molecules in both structures are associated via van der Waals interactions forming cavities occupied by solvent molecules. The structure refinement based on room-temperature data sets show significant disorder of the side chains of the cyclosporin A molecule with no adequate model of the solvent molecule in both structures. In contrast, the position of dibutylether was successfully localised using a low-temperature data set for 2. A series of isomorphous clathrates (cyclosporin A: solvent = 1 : 1) is reported. The structure of the tetrahydrofuran ( 1) and dibutylether (2) clathrates have been determined by X-ray single crystal diffraction. The cyclosporin molecules in both structures are associated via van der Waals interactions forming cavities occupied by solvent molecules. The structure refinement based on room-temperature data sets show significant disorder of the side chains of the cyclosporin A molecule with no adequate model of the solvent molecule in both structures. In contrast, the position of dibutylether was successfully localised using a low-temperature data set for 2. (en)
Title	Cyclosporins of symmetry P2(1) - a series of clathrates Cyclosporins of symmetry P2(1) - a series of clathrates (en)
skos:prefLabel	Cyclosporins of symmetry P2(1) - a series of clathrates Cyclosporins of symmetry P2(1) - a series of clathrates (en)
skos:notation	RIV/60076658:12640/00:00004747!RIV/2004/MSM/126404/N
http://linked.open.../vavai/riv/strany	137-153
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(VS96085), Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika	.
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Hušák, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Jihočeská univerzita v Českých Budějovicích / Ústav fyzikální biologie
http://linked.open...dnocenehoVysledku	737763
http://linked.open...ai/riv/idVysledku	RIV/60076658:12640/00:00004747
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cyclosporin A, X-ray structure analysis CRYSTAL, CONFORMATION (en)
http://linked.open.../riv/klicoveSlovo	CONFORMATION X-ray structure analysis CRYSTAL cyclosporin A
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[95CA2EFB1896]
http://linked.open...i/riv/nazevZdroje	Journal of Inclusion Phenomena and Macrocyclic Chemistry
http://linked.open...in/vavai/riv/obor	BO
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Studies of relations between function of biological membranes and interactions of their components
http://linked.open...UplatneniVysledku	2000
http://linked.open...v/svazekPeriodika	37
http://linked.open...iv/tvurceVysledku	Kratochvíl, Bohumil Cvak, Ladislav Žák, Zdirad Hušák, Michal Jegorov, Alexandr Pakhomova, Svetlana Buchta, Martin
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20143100011
issn	0923-0750
number of pages	16 (xsd:int)
http://localhost/t...ganizacniJednotka	12640

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