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  • This work described the retention of Cu from two different commonly used pesticides, the Bordeaux mixture (CuSO4 + Ca(OH)2) and Cu-oxychloride (3Cu(OH)2?CuCl2), and from Cu(NO3)2 in contrasting soil types (Leptosol, Chernozem, Cambisol). Thermodynamic modeling showed that Cu speciation was similar in all fungicide solutions. However, the retention of Cu differed with the fungicide used (maximum retention from the Bordeaux mixture) which indicates that different retention processes occurred in the studied soils. The suggested mechanisms include: specific and non-specific adsorption (especially on soil organic matter), precipitation of newly formed phases, such as CuO, Cu(OH)2, Cu2(OH)3NO3, CuCO3/Cu2(OH)2CO3 and in the case of the Bordeaux mixture, precipitation of various Cu-hydroxysulfates. These phases were identified by the speciation model. The retention of fungicide-derived Cu in the studied soil types followed well the Freundlich isotherm and was directly controlled by the chemical form of Cu. A
  • This work described the retention of Cu from two different commonly used pesticides, the Bordeaux mixture (CuSO4 + Ca(OH)2) and Cu-oxychloride (3Cu(OH)2?CuCl2), and from Cu(NO3)2 in contrasting soil types (Leptosol, Chernozem, Cambisol). Thermodynamic modeling showed that Cu speciation was similar in all fungicide solutions. However, the retention of Cu differed with the fungicide used (maximum retention from the Bordeaux mixture) which indicates that different retention processes occurred in the studied soils. The suggested mechanisms include: specific and non-specific adsorption (especially on soil organic matter), precipitation of newly formed phases, such as CuO, Cu(OH)2, Cu2(OH)3NO3, CuCO3/Cu2(OH)2CO3 and in the case of the Bordeaux mixture, precipitation of various Cu-hydroxysulfates. These phases were identified by the speciation model. The retention of fungicide-derived Cu in the studied soil types followed well the Freundlich isotherm and was directly controlled by the chemical form of Cu. A (en)
Title
  • Retention of copper originating from different fungicides in contrasting soil types
  • Retention of copper originating from different fungicides in contrasting soil types (en)
skos:prefLabel
  • Retention of copper originating from different fungicides in contrasting soil types
  • Retention of copper originating from different fungicides in contrasting soil types (en)
skos:notation
  • RIV/60076658:12220/09:00010909!RIV10-MSM-12220___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP526/08/P042), S, Z(MSM0021620855), Z(MSM6007665806), Z(MSM6046070901)
http://linked.open...iv/cisloPeriodika
  • 2-3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 339238
http://linked.open...ai/riv/idVysledku
  • RIV/60076658:12220/09:00010909
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • copper oxychloride; Bordeaux mixture; isotherm; sorption; soil contamination; pesticide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • BE - Belgické království
http://linked.open...ontrolniKodProRIV
  • [66D9F7F4DD2E]
http://linked.open...i/riv/nazevZdroje
  • Journal of Hazardous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 166
http://linked.open...iv/tvurceVysledku
  • Komárek, Michael
  • Száková, Jiřina
  • Balík, Jiří
  • Chrastný, Vladislav
  • Drahota, Petr
  • Vaněk, Aleš
  • Kubová, Karolína
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-3894
number of pages
http://localhost/t...ganizacniJednotka
  • 12220
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