About: Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function

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About: Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	From extraction experiments and gamma-activity measurements, the exchange extraction constantcorresponding to the general equilibrium Ca2+(aq) + 2HL(nb) double left right arrow CaL2(nb) + 2H(+)(aq) taking place in the two-phase water-nitrobenzene (L- = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K-ex(Ca2+, 2HL) = 0.0 +/- 0.1. Further, the stability constant of the electroneutral complex species CaL2 in water-saturated nitrobenzene was calculated for a temperature of 25 degrees C : log beta(nb) (CaL2) = 11.0 +/- 0.2. From extraction experiments and gamma-activity measurements, the exchange extraction constantcorresponding to the general equilibrium Ca2+(aq) + 2HL(nb) double left right arrow CaL2(nb) + 2H(+)(aq) taking place in the two-phase water-nitrobenzene (L- = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K-ex(Ca2+, 2HL) = 0.0 +/- 0.1. Further, the stability constant of the electroneutral complex species CaL2 in water-saturated nitrobenzene was calculated for a temperature of 25 degrees C : log beta(nb) (CaL2) = 11.0 +/- 0.2. (en)
Title	Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function (en)
skos:prefLabel	Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function (en)
skos:notation	RIV/46356088:_____/12:#0001252!RIV13-MPO-46356088
http://linked.open...avai/riv/aktivita	N S
http://linked.open...avai/riv/aktivity	N, S
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Selucký, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	ÚJV Řež, a. s.
http://linked.open...dnocenehoVysledku	169156
http://linked.open...ai/riv/idVysledku	RIV/46356088:_____/12:#0001252
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Calcium; anionic ligand with CMPO function; complexation; extraction and stability constants; water-nitrobenzene system (en)
http://linked.open.../riv/klicoveSlovo	Calcium extraction and stability constants water-nitrobenzene system complexation anionic ligand with CMPO function
http://linked.open...odStatuVydavatele	SI - Slovinská republika
http://linked.open...ontrolniKodProRIV	[FC764126E135]
http://linked.open...i/riv/nazevZdroje	Acta Chimica Slovenica
http://linked.open...in/vavai/riv/obor	CH
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	59
http://linked.open...iv/tvurceVysledku	Makrlík, Emanuel Selucký, Pavel
http://linked.open...ain/vavai/riv/wos	000305826700029
issn	1318-0207
number of pages	4 (xsd:int)

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