About: Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function     Goto   Sponge   NotDistinct   Permalink

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  • From extraction experiments and -activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq) + CaL2(nb) ML2(nb) + Ca2+(aq) taking place in the two-phase water-nitrobenzene system (M2+ = Mg2+, Sr2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, , Co2+, Ni2+, Mn2+; = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the electroneutral complex species ML2 in water-saturated nitrobenzene were calculated; they were found to increase in the following cation order: Sr2+ < Ba2+, Ni2+ < Mg2+ < Co2+ < Zn2+, Cd2+ < Mn2+ < Cu2+ < Pb2+ < .
  • From extraction experiments and -activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq) + CaL2(nb) ML2(nb) + Ca2+(aq) taking place in the two-phase water-nitrobenzene system (M2+ = Mg2+, Sr2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, , Co2+, Ni2+, Mn2+; = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the electroneutral complex species ML2 in water-saturated nitrobenzene were calculated; they were found to increase in the following cation order: Sr2+ < Ba2+, Ni2+ < Mg2+ < Co2+ < Zn2+, Cd2+ < Mn2+ < Cu2+ < Pb2+ < . (en)
Title
  • Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function
  • Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function (en)
skos:prefLabel
  • Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function
  • Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function (en)
skos:notation
  • RIV/46356088:_____/12:#0001248!RIV13-MPO-46356088
http://linked.open...avai/riv/aktivita
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  • N, S
http://linked.open...iv/cisloPeriodika
  • 1
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http://linked.open...aciTvurceVysledku
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  • 169159
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  • RIV/46356088:_____/12:#0001248
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  • Cobalt bis(dicarbollide) anion; Divalent metal cations; Extraction; Nitrobenzene; Stability constants (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [69E40729F0A1]
http://linked.open...i/riv/nazevZdroje
  • Journal of Radioanalytical and Nuclear Chemistry
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http://linked.open...UplatneniVysledku
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  • 293
http://linked.open...iv/tvurceVysledku
  • Makrlík, Emanuel
  • Selucký, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000305228200014
issn
  • 0236-5731
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10967-012-1770-6
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