About: Solvent extraction of H3O+, NH4 (+), Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor

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About: Solvent extraction of H3O+, NH4 (+), Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	From extraction experiments and c-activity measurements, the extraction constants corresponding to the general equilibrium M+(aq) + 1.Cs+(nb) reversible arrow 1.M+(nb) + Cs+(aq) taking part in the two-phase water-nitrobenzene system (1 = hexaarylbenzene-based receptor; M+ = H3O+, NH4+, Ag+, K+, Rb+, Tl+; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the series of Rb+ < K+ < Ag+, Tl+ < H3O+, NH4+. From extraction experiments and c-activity measurements, the extraction constants corresponding to the general equilibrium M+(aq) + 1.Cs+(nb) reversible arrow 1.M+(nb) + Cs+(aq) taking part in the two-phase water-nitrobenzene system (1 = hexaarylbenzene-based receptor; M+ = H3O+, NH4+, Ag+, K+, Rb+, Tl+; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the series of Rb+ < K+ < Ag+, Tl+ < H3O+, NH4+. (en)
Title	Solvent extraction of H3O+, NH4 (+), Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor Solvent extraction of H3O+, NH4 (+), Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor (en)
skos:prefLabel	Solvent extraction of H3O+, NH4 (+), Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor Solvent extraction of H3O+, NH4 (+), Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor (en)
skos:notation	RIV/46356088:_____/11:#0001154!RIV12-MPO-46356088
http://linked.open...avai/riv/aktivita	N S Z
http://linked.open...avai/riv/aktivity	N, S, Z(AV0Z40500505), Z(MSM4977751303)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Selucký, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	ÚJV Řež, a. s.
http://linked.open...dnocenehoVysledku	230560
http://linked.open...ai/riv/idVysledku	RIV/46356088:_____/11:#0001154
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Univalent ions; Hexaarylbenzene-based receptor; Dicarbollylcobaltate; Extraction; Nitrobenzene; Stability constants (en)
http://linked.open.../riv/klicoveSlovo	Dicarbollylcobaltate Nitrobenzene Stability constants Hexaarylbenzene-based receptor Univalent ions Extraction
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[3B36B26283E9]
http://linked.open...i/riv/nazevZdroje	Journal of Radioanalytical and Nuclear Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	287
http://linked.open...iv/tvurceVysledku	Makrlík, Emanuel Selucký, Pavel
http://linked.open...ain/vavai/riv/wos	000286332100019
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů.
issn	0236-5731
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10967-010-0704-4

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