About: Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polypropylene glycol PPG 425     Goto   Sponge   NotDistinct   Permalink

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  • Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H(+)B(-)) in the presence of polypropylene glycol PPG 425 (L) has been investigated. The equilibrium data have been explained assuming that the species HL ?, CaL(2+) and SrL(2+) (L = PPG 425) are extracted into the organic phase. The values of extraction and stability constants of the cationic complex species in nitrobenzene saturated with water have been determined. It was found that in water-saturated nitrobenzene, the stability constant of the complex SrL(2+), where L is PPG 425, is somewhat higher than that of the species CaL(2+) with the same ligand L.
  • Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H(+)B(-)) in the presence of polypropylene glycol PPG 425 (L) has been investigated. The equilibrium data have been explained assuming that the species HL ?, CaL(2+) and SrL(2+) (L = PPG 425) are extracted into the organic phase. The values of extraction and stability constants of the cationic complex species in nitrobenzene saturated with water have been determined. It was found that in water-saturated nitrobenzene, the stability constant of the complex SrL(2+), where L is PPG 425, is somewhat higher than that of the species CaL(2+) with the same ligand L. (en)
Title
  • Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polypropylene glycol PPG 425
  • Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polypropylene glycol PPG 425 (en)
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  • Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polypropylene glycol PPG 425
  • Solvent extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of polypropylene glycol PPG 425 (en)
skos:notation
  • RIV/46356088:_____/11:#0001147!RIV12-MPO-46356088
http://linked.open...avai/riv/aktivita
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  • N, S, Z(MSM4977751303)
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  • 1
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  • 230554
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  • RIV/46356088:_____/11:#0001147
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  • Extraction; Calcium; Strontium; Dicarbollylcobaltate; Water-nitrobenzene system; Polypropylene glycol PPG 425 (en)
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  • NL - Nizozemsko
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  • [AA0403C95CB2]
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  • Journal of radioanalytical and nuclear chemistry
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  • 287
http://linked.open...iv/tvurceVysledku
  • Makrlík, Emanuel
  • Selucký, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000286333400021
http://linked.open...n/vavai/riv/zamer
issn
  • 0236-5731
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10967-010-0660-z
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