About: Electrocapillary activity and adsorptive accumulation of U(VI)-chloranilic acid complexes on mercury electrode

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About: Electrocapillary activity and adsorptive accumulation of U(VI)-chloranilic acid complexes on mercury electrode Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Byla studována mezifázová aktivita komplexů uranu(VI) s cupferronem a kyselinou chloranilovou (CAA) (v 0.1 M acetátovém pufru pH 4.6 a 0.1 M NaClO4) na polarizované rtuťové elektrodě při 110 mV, 10 mV a -240 mV vs. nasycená kalomelová elektroda (SKE) za použití adsorptivních stripping voltametrických metod. Byl pozorován kompetitivní efekt mezifázové aktivity zmíněných komplexů spočívající v nemonotonním vlivu objemové koncentrace U(VI) na adsorpci zmíněných komplexotvorných činidel za jejich konstantní objemové koncentrace. (cs) Interfacial activity of uranium(VI)-cupferron and uranium(VI)-chloranilic acid (CAA) complexes (in 0.1 M acetate buffer pH 4.6 or 0.1 M NaClO4 respectively) on polarized mercury electrode at 110 mV, 10 mV or -240 mV respectively vs. saturated calomel electrode (SCE), and under conditions of the application of adsorptive stripping voltammetric techniques was studied. It revealed a competitive effect of interfacial activity of the mentioned complexes consisting in a nonmonotonous effect of the bulk concentration of U(VI) on the adsorption of the mentioned complexing reagents at their constant concentrations. Interfacial activity of uranium(VI)-cupferron and uranium(VI)-chloranilic acid (CAA) complexes (in 0.1 M acetate buffer pH 4.6 or 0.1 M NaClO4 respectively) on polarized mercury electrode at 110 mV, 10 mV or -240 mV respectively vs. saturated calomel electrode (SCE), and under conditions of the application of adsorptive stripping voltammetric techniques was studied. It revealed a competitive effect of interfacial activity of the mentioned complexes consisting in a nonmonotonous effect of the bulk concentration of U(VI) on the adsorption of the mentioned complexing reagents at their constant concentrations. (en)
Title	Electrocapillary activity and adsorptive accumulation of U(VI)-chloranilic acid complexes on mercury electrode Electrocapillary activity and adsorptive accumulation of U(VI)-chloranilic acid complexes on mercury electrode (en) Elektrokapilární aktivita a adsorptivní akumulace komplexů cupferronu a kyseliny chloranilové s uranem(VI) na rtuťové elektrodě (cs)
skos:prefLabel	Electrocapillary activity and adsorptive accumulation of U(VI)-chloranilic acid complexes on mercury electrode Electrocapillary activity and adsorptive accumulation of U(VI)-chloranilic acid complexes on mercury electrode (en) Elektrokapilární aktivita a adsorptivní akumulace komplexů cupferronu a kyseliny chloranilové s uranem(VI) na rtuťové elektrodě (cs)
skos:notation	RIV/15273440:_____/03:00009815!RIV/2005/MSM/734405/N
http://linked.open.../vavai/riv/strany	1687-1992
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(OE92)
http://linked.open...iv/cisloPeriodika	21
http://linked.open...vai/riv/dodaniDat	2005
http://linked.open...aciTvurceVysledku	Novotný, Ladislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	POLARO-SENSORS, spol. s r.o. v likvidaci
http://linked.open...dnocenehoVysledku	605609
http://linked.open...ai/riv/idVysledku	RIV/15273440:_____/03:00009815
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Interfacial activity;Uranium-complexes;Cupferron;Chloranilic acid;Adsorption voltammetry (en)
http://linked.open.../riv/klicoveSlovo	Adsorption voltammetry Chloranilic acid Cupferron Interfacial activity Uranium-complexes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[1197FB168A1F]
http://linked.open...i/riv/nazevZdroje	Electroanalysis
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Research and development and introduction into production of specified version of the combined chronopotentiometric/voltammetric portable analyzer for determination of toxic species in aqueous solutions and biological fluids.
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	15
http://linked.open...iv/tvurceVysledku	Novotný, Ladislav
issn	1040-0397
number of pages	6 (xsd:int)

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