About: Selective Hydrogen Detection with TiO2 Nanofilm via the Porous-Alumina-Assisted Anodizing of Titanium Layers     Goto   Sponge   NotDistinct   Permalink

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  • Nanostructured metal oxides grown via porous-alumina (PA)-assisted anodization of sputtered refractory metals are of increasing interest as active layers for gas microsensors. Although nanostructured titanium oxide is particularly attractive, PA-assisted anodic formation of titanium oxide nanostructures remains a challenge because of their chemical instability caused by substantially mixing titania with alumina during film growth. Here we advance the approach and employ a unique combination of electrical and electrolytic conditions to achieve the PA-assisted formation of a stable amorphous TiO2 nanofilm on dielectric substrates, followed by high-temperature annealing to attain crystallization and enhance semiconductor properties of the film. A laboratory-scale microsensor employing the TiO2 nanofilm as active layer shows good sensitivity and selectivity to hydrogen against ethanol and carbon monoxide, which is in demand for proton-exchange fuel-cell applications.
  • Nanostructured metal oxides grown via porous-alumina (PA)-assisted anodization of sputtered refractory metals are of increasing interest as active layers for gas microsensors. Although nanostructured titanium oxide is particularly attractive, PA-assisted anodic formation of titanium oxide nanostructures remains a challenge because of their chemical instability caused by substantially mixing titania with alumina during film growth. Here we advance the approach and employ a unique combination of electrical and electrolytic conditions to achieve the PA-assisted formation of a stable amorphous TiO2 nanofilm on dielectric substrates, followed by high-temperature annealing to attain crystallization and enhance semiconductor properties of the film. A laboratory-scale microsensor employing the TiO2 nanofilm as active layer shows good sensitivity and selectivity to hydrogen against ethanol and carbon monoxide, which is in demand for proton-exchange fuel-cell applications. (en)
Title
  • Selective Hydrogen Detection with TiO2 Nanofilm via the Porous-Alumina-Assisted Anodizing of Titanium Layers
  • Selective Hydrogen Detection with TiO2 Nanofilm via the Porous-Alumina-Assisted Anodizing of Titanium Layers (en)
skos:prefLabel
  • Selective Hydrogen Detection with TiO2 Nanofilm via the Porous-Alumina-Assisted Anodizing of Titanium Layers
  • Selective Hydrogen Detection with TiO2 Nanofilm via the Porous-Alumina-Assisted Anodizing of Titanium Layers (en)
skos:notation
  • RIV/00216305:26620/14:PU111724!RIV15-GA0-26620___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA14-29531S)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
  • Mozalev, Alexander
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  • 44293
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  • RIV/00216305:26620/14:PU111724
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  • nanostructured metal oxides, anodizing, porous alumina, titanium oxide, hydrogen sensor (en)
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  • [64D191913D76]
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  • Valencia, Spain
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  • IEEE Service Center 445 Hoes Lane Piscataway, NJ
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  • Proceedings of IEEE sensors 2014
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  • Mozalev, Alexander
  • Gispert-Guirado, Francesc
  • Llobet, Eduard
  • Vazquez, Rosa Maria
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
number of pages
http://bibframe.org/vocab/doi
  • 10.1109/ICSENS.2014.6985122
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  • IEEE
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  • 978-1-4799-0161-6
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  • 26620
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