About: Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4) EtOH H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied. The complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4) EtOH H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied. (en)
Title	Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity (en)
skos:prefLabel	Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity (en)
skos:notation	RIV/00216305:26620/14:PU110419!RIV15-MSM-26620___
http://linked.open...avai/riv/aktivita	I P V
http://linked.open...avai/riv/aktivity	I, P(ED1.1.00/02.0068), P(LO1204), V
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Adam, Vojtěch Kizek, René Kopel, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoké učení technické v Brně / Středoevropský technologický institut
http://linked.open...dnocenehoVysledku	51315
http://linked.open...ai/riv/idVysledku	RIV/00216305:26620/14:PU110419
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	trithiocyanuric acid, trimercaptotriazine, crystal structure, complexes, acetylcholinesterase activity, Schiff base (en)
http://linked.open.../riv/klicoveSlovo	trithiocyanuric acid complexes crystal structure Schiff base acetylcholinesterase activity trimercaptotriazine
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[3982F9C417BB]
http://linked.open...i/riv/nazevZdroje	MOLECULES
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Central european institute of technology Udržitelný rozvoj výzkumu v Centru regionu Haná
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	19
http://linked.open...iv/tvurceVysledku	Adam, Vojtěch Doležal, Karel Kizek, René Kuča, Kamil Jun, Daniel Kopel, Pavel Langer, Vratislav
issn	1420-3049
number of pages	17 (xsd:int)
http://localhost/t...ganizacniJednotka	26620

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