About: Biodegradable polyhydroxybutyrate as a polyol for elastomeric polyurethanes     Goto   Sponge   NotDistinct   Permalink

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  • In the proposed work, new elastomeric bio-polyol based polyurethanes (bio-PUs) with specific mechanical properties were prepared by a one-shot process without the presence of a solvent. Commercial non-degradable polyether polyol derived from petrochemical feed stock was partly (in the amount of 1 mass %, 5 mass %, and 10 mass %) substituted by the biodegradable polyhydroxybutyrate (PHB). Morphology of elastomeric PU composites was evaluated by scanning electron microscopy and mechanical properties of the prepared samples were obtained by both tensile measurements and prediction via the Mooney-Rivlin equation. Electron microscopy proved that the prepared materials have the character of a particle filled composite material, where PHB particles are regular with their size of about 1–2 microm in diameter. Tensil measurements demonstrated that the Youngs modulus, tensile stress at break, and tensile strain at break of each sample increase with the increase of the volume fraction of the filler. From the m
  • In the proposed work, new elastomeric bio-polyol based polyurethanes (bio-PUs) with specific mechanical properties were prepared by a one-shot process without the presence of a solvent. Commercial non-degradable polyether polyol derived from petrochemical feed stock was partly (in the amount of 1 mass %, 5 mass %, and 10 mass %) substituted by the biodegradable polyhydroxybutyrate (PHB). Morphology of elastomeric PU composites was evaluated by scanning electron microscopy and mechanical properties of the prepared samples were obtained by both tensile measurements and prediction via the Mooney-Rivlin equation. Electron microscopy proved that the prepared materials have the character of a particle filled composite material, where PHB particles are regular with their size of about 1–2 microm in diameter. Tensil measurements demonstrated that the Youngs modulus, tensile stress at break, and tensile strain at break of each sample increase with the increase of the volume fraction of the filler. From the m (en)
Title
  • Biodegradable polyhydroxybutyrate as a polyol for elastomeric polyurethanes
  • Biodegradable polyhydroxybutyrate as a polyol for elastomeric polyurethanes (en)
skos:prefLabel
  • Biodegradable polyhydroxybutyrate as a polyol for elastomeric polyurethanes
  • Biodegradable polyhydroxybutyrate as a polyol for elastomeric polyurethanes (en)
skos:notation
  • RIV/00216305:26620/12:PU99352!RIV13-MSM-26620___
http://linked.open...avai/riv/aktivita
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  • S
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  • 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 125004
http://linked.open...ai/riv/idVysledku
  • RIV/00216305:26620/12:PU99352
http://linked.open...riv/jazykVysledku
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  • polyurethanes, elastomers, biodegradable, poly(hydroxybutyrate), simulation, Mooney– Rivlin equation (en)
http://linked.open.../riv/klicoveSlovo
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  • SK - Slovenská republika
http://linked.open...ontrolniKodProRIV
  • [FCF4C94132A7]
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  • Chemical Papers
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http://linked.open...v/svazekPeriodika
  • 66
http://linked.open...iv/tvurceVysledku
  • Jančář, Josef
  • Kupka, Vojtěch
  • Sedláček, Petr
  • Vojtová, Lucy
  • Wasserbauer, Jaromír
  • Žídek, Jan
issn
  • 0366-6352
number of pages
http://localhost/t...ganizacniJednotka
  • 26620
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