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  • Analytical and physical-chemical techniques, such as elemental analysis, FTIR, surface tension (ST) measurement, high performance size exclusion chromatography (HPSEC) and high resolution ultrasonic spectroscopy (HRUS) were combined in order to assess the surface activity of lignite sodium humic acids salts (humates). Humates were obtained from parental and modified South Moravian lignite pretreated either by oxidation or by small organic acids. It was shown that unlike common surfactants, humates dissolved in water do not exhibit the critical micelle concentration and form micelle-like aggregates also in diluted solutions. As revealed by HRUS, the aggregation and/or reconformation of humic aggregates in solution takes up to ten minutes; in contrast, the ST measurements showed long-term stabilization associated with a slow decrease in ST of the solution. Correlation with results of HPSEC indicated that the surface activity of lignite humates is caused predominantly by aggregates with apparent molecula
  • Analytical and physical-chemical techniques, such as elemental analysis, FTIR, surface tension (ST) measurement, high performance size exclusion chromatography (HPSEC) and high resolution ultrasonic spectroscopy (HRUS) were combined in order to assess the surface activity of lignite sodium humic acids salts (humates). Humates were obtained from parental and modified South Moravian lignite pretreated either by oxidation or by small organic acids. It was shown that unlike common surfactants, humates dissolved in water do not exhibit the critical micelle concentration and form micelle-like aggregates also in diluted solutions. As revealed by HRUS, the aggregation and/or reconformation of humic aggregates in solution takes up to ten minutes; in contrast, the ST measurements showed long-term stabilization associated with a slow decrease in ST of the solution. Correlation with results of HPSEC indicated that the surface activity of lignite humates is caused predominantly by aggregates with apparent molecula (en)
Title
  • Surface and Solution Behavior of Surfactants Produced from Lignite Humic Acids
  • Surface and Solution Behavior of Surfactants Produced from Lignite Humic Acids (en)
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  • Surface and Solution Behavior of Surfactants Produced from Lignite Humic Acids
  • Surface and Solution Behavior of Surfactants Produced from Lignite Humic Acids (en)
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  • RIV/00216305:26310/11:PU92956!RIV12-MSM-26310___
http://linked.open...avai/riv/aktivita
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  • Z(MSM0021630501)
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  • 7a
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  • 233480
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  • RIV/00216305:26310/11:PU92956
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  • Lignite humic acids, natural surfactants, ultrasonic resonator, size exclusion chromatography, surface tension (en)
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  • DE - Spolková republika Německo
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  • [B070F8F1CB53]
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  • Fresenius Environmental Bulletin
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  • 20
http://linked.open...iv/tvurceVysledku
  • Kučerík, Jiří
  • Čtvrtníčková, Anna
  • David, Jan
  • Drastík, Martin
http://linked.open...ain/vavai/riv/wos
  • 000292627300006
http://linked.open...n/vavai/riv/zamer
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  • 1018-4619
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  • 26310
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